Title :

Telomerization of butadiene with ethanol mediated by palladium N-heterocyclic carbene catalysts

Author(s) :

Palio, L. [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Dumont, Clement [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Suisse, Isabelle [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Sauthier, Mathieu [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Nolan, S. P. [Auteur]

Journal title :

Journal of Catalysis

Abbreviated title :

J. Catal.

Volume number :

429

Pages :

-

Publication date :

2024-01-11

ISSN :

0021-9517

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

The telomerization reaction of dienes with alcohols mediated by organopalladium complexes represents a versatile method to convert butadiene into value-added chemicals. In this contribution, we have examined the catalytic ...
Show more >The telomerization reaction of dienes with alcohols mediated by organopalladium complexes represents a versatile method to convert butadiene into value-added chemicals. In this contribution, we have examined the catalytic behavior of a series of well-defined palladium N-heterocyclic carbene precatalysts (Pd-NHC) in the telomerization of butadiene with ethanol. The bulky and less sterically demanding NHC ligands greatly influence yields and selectivity towards the linear product. With more hindered NHC ligands, the branched product is obtained in unprecedented higher amounts. The telomerization of butadiene with the renewable solketal leads to selective and complete conversion to product in minutes.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Submission date :

2024-01-20T00:59:02Z
2024-02-12T08:22:30Z