Titre :

Vapour-liquid equilibrium of acetone-CO2 mixtures of different compositions at the vicinity of the critical point

Auteur(s) :

Fabian, B. [Auteur]
Budapest University of Technology and Economics [Budapest] [BME]
Univers, Théorie, Interfaces, Nanostructures, Atmosphère et environnement, Molécules (UMR 6213) [UTINAM]
Horvai, G. [Auteur]
Idrissi, Nacer [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Jedlovszky, P. [Auteur]

Titre de la revue :

Journal of CO2 Utilization

Nom court de la revue :

J. CO2 Util.

Numéro :

34

Pagination :

465-471

Date de publication :

2019-12-21

ISSN :

2212-9820

Mot(s)-clé(s) en anglais :

Acetone-CO(2)mixtures
CO2-expanded liquids
Vapor-liquid equilibrium
Thermodynamic data
Critical point
Surface tension

Discipline(s) HAL :

Chimie

Résumé en anglais : [en]

The vapour-liquid equilibrium of acetone−CO2 mixtures is studied by computer simulation at 11 different compositions, ranging from neat CO2 to neat acetone, in a 50–100 K wide range of temperatures at the vicinity of the ...
Lire la suite >The vapour-liquid equilibrium of acetone−CO2 mixtures is studied by computer simulation at 11 different compositions, ranging from neat CO2 to neat acetone, in a 50–100 K wide range of temperatures at the vicinity of the critical point. The composition dependence of the critical parameters is determined, for the first time, in the entire composition range. It is found that while the critical temperature changes monotonically with the composition, the critical pressure goes through a maximum around the acetone mole fraction value of 0.3, and the critical density might also exhibit a maximum in the acetone mole fraction range of 0-0.2. Temperature dependence of the surface tension is also determined in the entire composition range. The obtained results agree, in general, well with experimental data; their deviation remains below the range within which different experimental data sets deviate from each other. Since experimental data in this respect exist, unfortunately, only in limited ranges of compositions (at low acetone mole fractions) and temperatures (data above about 335 K are scarce), the present study largely extends the range of thermodynamic conditions in which we have reliable information on the liquid-vapour equilibrium and critical conditions of acetone−CO2 mixtures.Lire moins >

Langue :

Anglais

Comité de lecture :

Oui

Audience :

Internationale

Vulgarisation :

Non

Établissement(s) :

Université de Lille
CNRS

Collections :

• Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516

Date de dépôt :

2024-02-28T23:16:56Z
2024-03-11T10:38:59Z