Title :

Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction

Author(s) :

Mifleur, Alexis [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Mortreux, Andre [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Suisse, Isabelle [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Sauthier, Mathieu [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]

Journal title :

Molecular Catalysis

Volume number :

427

Pages :

25-30

Publisher :

Elsevier

Publication date :

2017-02

HAL domain(s) :

Chimie/Catalyse
Chimie/Chimie de coordination

English abstract : [en]

The catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining ...
Show more >The catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining 100% glycerol conversion into a mixture of glyceryl mono- and dibutenyl ethers. The experimental protocols used involved batch experiments or continuous feeding of butadiene at atmospheric pressure. The reaction has then been scaled up to produce multigrams of each pure monoethers and diethers according to simple decantation/distillation procedures. The ethers were further hydrogenated to their corresponding alkyl glyceryl ethers.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Catalyse de polymérisation
Catalyse et synthèse éco-compatible (CASECO)
Méthodologie organométallique pour la catalyse homogène (MOCAH)

Submission date :

2019-09-25T14:05:33Z
2021-03-29T15:30:57Z