Synthesis of C4 chain glyceryl ethers via ...
Document type :
Article dans une revue scientifique: Article original
Permalink :
Title :
Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction
Author(s) :
Mifleur, Alexis [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Mortreux, Andre [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Suisse, Isabelle [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Sauthier, Mathieu [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Mortreux, Andre [Auteur]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Suisse, Isabelle [Auteur]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Sauthier, Mathieu [Auteur]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Journal title :
Molecular Catalysis
Volume number :
427
Pages :
25-30
Publisher :
Elsevier
Publication date :
2017-02
HAL domain(s) :
Chimie/Catalyse
Chimie/Chimie de coordination
Chimie/Chimie de coordination
English abstract : [en]
The catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining ...
Show more >The catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining 100% glycerol conversion into a mixture of glyceryl mono- and dibutenyl ethers. The experimental protocols used involved batch experiments or continuous feeding of butadiene at atmospheric pressure. The reaction has then been scaled up to produce multigrams of each pure monoethers and diethers according to simple decantation/distillation procedures. The ethers were further hydrogenated to their corresponding alkyl glyceryl ethers.Show less >
Show more >The catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining 100% glycerol conversion into a mixture of glyceryl mono- and dibutenyl ethers. The experimental protocols used involved batch experiments or continuous feeding of butadiene at atmospheric pressure. The reaction has then been scaled up to produce multigrams of each pure monoethers and diethers according to simple decantation/distillation procedures. The ethers were further hydrogenated to their corresponding alkyl glyceryl ethers.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Catalyse de polymérisation
Catalyse et synthèse éco-compatible (CASECO)
Méthodologie organométallique pour la catalyse homogène (MOCAH)
Catalyse et synthèse éco-compatible (CASECO)
Méthodologie organométallique pour la catalyse homogène (MOCAH)
Submission date :
2019-09-25T14:05:33Z
2021-03-29T15:30:57Z
2021-03-29T15:30:57Z