Activated Glycerol Carbonates, Versatile ...
Type de document :
Article dans une revue scientifique
DOI :
URL permanente :
Titre :
Activated Glycerol Carbonates, Versatile Reagents with Aliphatic Amines: Formation and Reactivity of Glycidyl Carbamates and Trialkylamines
Auteur(s) :
Legros, Vanessa [Auteur]
Taing, Guillaume [Auteur]
Buisson, Pierre [Auteur]
Schuler, Marie [Auteur]
Bostyn, Stéphane [Auteur]
Rousseau, Jolanta [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Sinturel, Christophe [Auteur]
Tatibouët, Arnaud [Auteur]
Taing, Guillaume [Auteur]
Buisson, Pierre [Auteur]
Schuler, Marie [Auteur]
Bostyn, Stéphane [Auteur]
Rousseau, Jolanta [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Sinturel, Christophe [Auteur]
Tatibouët, Arnaud [Auteur]
Titre de la revue :
European Journal of Organic Chemistry
Numéro :
2017
Pagination :
5032-5043
Date de publication :
2017-07-19
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
The reactivity of mesylated and tosylated glycerol carbonate towards secondary and tertiary amines has been studied, and allowed regioselective access to carbamates which could then be transformed into glycidyl carbamates. ...
Lire la suite >The reactivity of mesylated and tosylated glycerol carbonate towards secondary and tertiary amines has been studied, and allowed regioselective access to carbamates which could then be transformed into glycidyl carbamates. By tuning the reaction conditions, we were able to direct the reaction towards the synthesis of new 5-aminomethyldioxolan-2-one derivatives. The opening of glycidyl carbamates with various amines was also explored, and showed the opportunity to use glycerol as a linker between two different amine moieties.Lire moins >
Lire la suite >The reactivity of mesylated and tosylated glycerol carbonate towards secondary and tertiary amines has been studied, and allowed regioselective access to carbamates which could then be transformed into glycidyl carbamates. By tuning the reaction conditions, we were able to direct the reaction towards the synthesis of new 5-aminomethyldioxolan-2-one derivatives. The opening of glycidyl carbamates with various amines was also explored, and showed the opportunity to use glycerol as a linker between two different amine moieties.Lire moins >
Langue :
Anglais
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Université de Lille
Collections :
Équipe(s) de recherche :
Catalyse et chimie supramoléculaire (CASU)
Date de dépôt :
2019-09-25T14:05:48Z