Title :

Highly dispersed copper (oxide) nanoparticles prepared on SBA-15 partially occluded with the P123 surfactant: toward the design of active hydrogenation catalysts

Author(s) :

Dragoi, Brindusa [Auteur]
Mazilu, Irina [Auteur]
Chirieac, Alexandru [Auteur]
Ciotonea, Carmen [Auteur]
Ungureanu, Adrian [Auteur]
Marceau, Eric [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Dumitriu, Emil [Auteur]
Royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Journal title :

Catalysis Science & Technology

Volume number :

7

Pages :

5376-5385

Publication date :

2017-07-24

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

Copper (oxide) nanoparticles with dispersion and size ranging from highly dispersed nanoparticles confined within the intra-wall pores to nanoparticles confined within the main mesopores can be simply produced via incipient ...
Show more >Copper (oxide) nanoparticles with dispersion and size ranging from highly dispersed nanoparticles confined within the intra-wall pores to nanoparticles confined within the main mesopores can be simply produced via incipient wetness impregnation by using mesoporous silica supports containing the structure directing agent P123 partially occluding the intra-wall pores of SBA-15. Remarkably high copper dispersions of 69.5 down to 25.9% for metal loadings from 5 to 20 wt% were achieved as a result of the dual effect of the presence of surface silanol groups and the unique confining space between the silica walls and residual P123 in the intra-wall pores. The copper catalysts demonstrated outstanding activities in the hydrogenation of cinnamaldehyde, with TOF values ranging from 5.1 × 10−3 to 22.1 × 10−3 s−1, which are much higher than those of other supported copper catalysts reported elsewhere and prepared using conventional approaches.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Matériaux pour la catalyse (MATCAT)

Submission date :

2019-09-25T14:06:30Z