Autothermal reforming of model purified ...
Document type :
Article dans une revue scientifique
Permalink :
Title :
Autothermal reforming of model purified biogas using an extruded honeycomb monolith: A new catalyst based on nickel incorporated illite clay promoted with MgO
Author(s) :
Akri, Mohcin [Auteur]
Achak, Ouafae [Auteur]
Granger, Pascal [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Wang, Sheng [Auteur]
Batiot-Dupeyrat, Catherine [Auteur]
Chafik, Tarik [Auteur]
Achak, Ouafae [Auteur]
Granger, Pascal [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Wang, Sheng [Auteur]
Batiot-Dupeyrat, Catherine [Auteur]
Chafik, Tarik [Auteur]
Journal title :
Journal of Cleaner Production
Volume number :
171
Pages :
377-389
Publisher :
Elsevier
Publication date :
2018-01-10
English keyword(s) :
Monolith
Natural clay
Extrusion
Magnesium
Nickel
Autothermal dry reforming
Natural clay
Extrusion
Magnesium
Nickel
Autothermal dry reforming
HAL domain(s) :
Chimie/Catalyse
English abstract : [en]
The dry reforming of methane was investigated using a novel catalyst based on natural illite clay to which nickel and magnesium has been added into moldable paste easily extrudated into honeycomb monolith. This approach ...
Show more >The dry reforming of methane was investigated using a novel catalyst based on natural illite clay to which nickel and magnesium has been added into moldable paste easily extrudated into honeycomb monolith. This approach can represent a significant breakthrough offering an alternative to conventional costly wash-coated ceramic substrates usually difficult to optimize, and a gain in efficiency thanks to the minimization of transfer limitations. The best catalytic performance were obtained with illite clay containing 8 wt.%Ni and 3 wt.%Mg, yielding to excellent conversions of CH4 and CO2 at 800 °C of respectively 81% and 76%. The catalytic enhancement observed on magnesium-doped systems was attributed to the stabilization of smaller Ni particles associated with the formation of NiO-MgO solid solution which slows down particle sintering. The obtained results suggest different types of nickel-support interactions in addition to improved basic properties inducing synergy effects on the rate of methane and CO2 conversion and higher resistance to deactivation phenomena.Show less >
Show more >The dry reforming of methane was investigated using a novel catalyst based on natural illite clay to which nickel and magnesium has been added into moldable paste easily extrudated into honeycomb monolith. This approach can represent a significant breakthrough offering an alternative to conventional costly wash-coated ceramic substrates usually difficult to optimize, and a gain in efficiency thanks to the minimization of transfer limitations. The best catalytic performance were obtained with illite clay containing 8 wt.%Ni and 3 wt.%Mg, yielding to excellent conversions of CH4 and CO2 at 800 °C of respectively 81% and 76%. The catalytic enhancement observed on magnesium-doped systems was attributed to the stabilization of smaller Ni particles associated with the formation of NiO-MgO solid solution which slows down particle sintering. The obtained results suggest different types of nickel-support interactions in addition to improved basic properties inducing synergy effects on the rate of methane and CO2 conversion and higher resistance to deactivation phenomena.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Remédiation et matériaux catalytiques (REMCAT)
Submission date :
2019-09-25T14:37:52Z
2021-03-17T11:39:21Z
2021-03-17T11:39:21Z