Title :

How Catalysts and Experimental Conditions Determine the Selective Hydroconversion of Furfural and 5-Hydroxymethylfurfural

Author(s) :

Chen, Shuo [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Wojcieszak, Robert [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Dumeignil, Franck [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Marceau, Eric [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Journal title :

Chemical Reviews

Volume number :

118

Pages :

11023-11117

Publication date :

2018

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

Furfural and 5-hydroxymethylfurfural stand out as bridges connectingbiomass raw materials to the biorefinery industry. Their reductive transformations byhydroconversion are key routes toward a wide variety of chemicals and ...
Show more >Furfural and 5-hydroxymethylfurfural stand out as bridges connectingbiomass raw materials to the biorefinery industry. Their reductive transformations byhydroconversion are key routes toward a wide variety of chemicals and biofuels, andheterogeneous catalysis plays a central role in these reactions. The catalyst efficiencyhighly depends on the nature of metals, supports, and additives, on the catalystpreparation procedure, and obviously on reaction conditions to which catalyst andreactants are exposed: solvent, pressure, and temperature. The present review focuseson the roles played by the catalyst at the molecular level in the hydroconversion offurfural and 5-hydroxymethylfurfural in the gas or liquid phases, including catalytichydrogen transfer routes and electro/photoreduction, into oxygenates or hydrocarbons(e.g., furfuryl alcohol, 2,5-bis(hydroxymethyl)furan, cyclopentanone, 1,5-pentanediol,2-methylfuran, 2,5-dimethylfuran, furan, furfuryl ethers, etc.). The mechanism ofadsorption of the reactant and the mechanism of the reaction of hydroconversion arecorrelated to the specificities of each active metal, both noble (Pt, Pd, Ru, Au, Rh, andIr) and non-noble (Ni, Cu, Co, Mo, and Fe), with an emphasis on the role of the support and of additives on catalyticperformances (conversion, yield, and stability). The reusability of catalytic systems (deactivation mechanism, protection, andregeneration methods) is also discussed.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

ENSCL
Université de Lille
CNRS
Centrale Lille
Univ. Artois

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Matériaux pour la catalyse (MATCAT)
Valorisation des alcanes et de la biomasse (VAALBIO)

Submission date :

2019-09-25T15:07:00Z
2019-10-07T16:50:27Z
2020-09-25T08:38:17Z