Electronic state spectroscopy of c-C5F8 ...
Type de document :
Compte-rendu et recension critique d'ouvrage
DOI :
PMID :
Titre :
Electronic state spectroscopy of c-C5F8 explored by photoabsorption, electron impact, photoelectron spectroscopies and ab initio calculations.
Auteur(s) :
Limão-Vieira, P. [Auteur]
Duflot, D. [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Vasekova, E. [Auteur]
Giuliani, Alexandre [Auteur]
Département Caractérisation et Elaboration des Produits Issus de l'Agriculture [CEPIA]
Synchrotron SOLEIL [SSOLEIL]
Lourenço, J. M. C. [Auteur]
Santos, P. M. [Auteur]
Instituto de Telecomunicações [Lisboa, Portugal]
Hoffman, S.V. [Auteur]
Centre for Storage Ring Facilities [Aarhus] [ISA]
Mason, N.J. [Auteur]
Delwiche, J. [Auteur]
Hubin-Franskin, M.-J. [Auteur]
Duflot, D. [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Vasekova, E. [Auteur]
Giuliani, Alexandre [Auteur]
Département Caractérisation et Elaboration des Produits Issus de l'Agriculture [CEPIA]
Synchrotron SOLEIL [SSOLEIL]
Lourenço, J. M. C. [Auteur]
Santos, P. M. [Auteur]
Instituto de Telecomunicações [Lisboa, Portugal]
Hoffman, S.V. [Auteur]
Centre for Storage Ring Facilities [Aarhus] [ISA]
Mason, N.J. [Auteur]
Delwiche, J. [Auteur]
Hubin-Franskin, M.-J. [Auteur]
Titre de la revue :
Journal of Physical Chemistry A
Pagination :
2782-93
Éditeur :
American Chemical Society
Date de publication :
2008-04-03
ISSN :
1089-5639
Mot(s)-clé(s) :
vuv photoabsorption
deposition
deposition
Mot(s)-clé(s) en anglais :
coupled-cluster theory
quantum-chemistry
excited-states
c5f8 plasmas
energies
octafluorocyclopentene
perfluorocyclopentene
molecule
quantum-chemistry
excited-states
c5f8 plasmas
energies
octafluorocyclopentene
perfluorocyclopentene
molecule
Discipline(s) HAL :
Chimie/Chimie théorique et/ou physique
Résumé en anglais : [en]
The electronic transitions and resonance-enhanced vibrational excitations of octafluorocyclopentene (c-C5F8) have been investigated using high-resolution photoabsorption spectroscopy in the energy range 6-11 eV. In addition, ...
Lire la suite >The electronic transitions and resonance-enhanced vibrational excitations of octafluorocyclopentene (c-C5F8) have been investigated using high-resolution photoabsorption spectroscopy in the energy range 6-11 eV. In addition, the high-resolution electron energy loss spectrum (HREELS) was recorded under the electric dipolar excitation conditions (100 eV incident energy, approximately 0 degrees scattering angle) over the 5-14 eV energy loss range. A He(I) photoelectron spectrum (PES) has also been recorded between 11 and 20 eV, allowing us to derive a more precise value of (11.288 +/- 0.002) eV for the ground neutral state adiabatic ionization energy. All spectra presented in this paper represent the first and highest resolution data yet reported for octafluorocyclopentene. Ab initio calculations have been performed for helping in the assignment of the spectral bands for both neutral excited states and ionic states.Lire moins >
Lire la suite >The electronic transitions and resonance-enhanced vibrational excitations of octafluorocyclopentene (c-C5F8) have been investigated using high-resolution photoabsorption spectroscopy in the energy range 6-11 eV. In addition, the high-resolution electron energy loss spectrum (HREELS) was recorded under the electric dipolar excitation conditions (100 eV incident energy, approximately 0 degrees scattering angle) over the 5-14 eV energy loss range. A He(I) photoelectron spectrum (PES) has also been recorded between 11 and 20 eV, allowing us to derive a more precise value of (11.288 +/- 0.002) eV for the ground neutral state adiabatic ionization energy. All spectra presented in this paper represent the first and highest resolution data yet reported for octafluorocyclopentene. Ab initio calculations have been performed for helping in the assignment of the spectral bands for both neutral excited states and ionic states.Lire moins >
Langue :
Anglais
Vulgarisation :
Non
Source :
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