Carbon dioxide transformation as a green ...
Type de document :
Compte-rendu et recension critique d'ouvrage
Titre :
Carbon dioxide transformation as a green alternative to phosgene and chloroformates: N-carboxy-alkylation of lactams and analogues.
Auteur(s) :
Homerin, Germain [Auteur]
Nica, Adrian Sorin [Auteur]
Abdel, Aitouche [Auteur]
Centre de Recherche en Informatique, Signal et Automatique de Lille - UMR 9189 [CRIStAL]
JUNIA [JUNIA]
Rigo, Benoit [Auteur]
Lipka, Emmanuelle [Auteur]
Ghinet, Alina [Auteur]
Nica, Adrian Sorin [Auteur]
Abdel, Aitouche [Auteur]
Centre de Recherche en Informatique, Signal et Automatique de Lille - UMR 9189 [CRIStAL]
JUNIA [JUNIA]
Rigo, Benoit [Auteur]
Lipka, Emmanuelle [Auteur]
Ghinet, Alina [Auteur]
Titre de la revue :
Journal of CO2 Utilization
Éditeur :
Elsevier
Date de publication :
2021-12-01
ISSN :
2212-9820
Mot(s)-clé(s) en anglais :
Carbon dioxide
Carbon capture and use
Carbon capture and use
Discipline(s) HAL :
Sciences de l'ingénieur [physics]/Automatique / Robotique
Résumé en anglais : [en]
A clean, safe, and efficient method for the N-carboxyalkylation of lactams was designed and studied in the current report. This three-component coupling of the substrate, carbon dioxide and an alkyl halide, has been ...
Lire la suite >A clean, safe, and efficient method for the N-carboxyalkylation of lactams was designed and studied in the current report. This three-component coupling of the substrate, carbon dioxide and an alkyl halide, has been developed as a green alternative to phosgene and chloroformates, and takes place at ambient temperature and low pressure of CO2. This provided an improved protocol for the protection of cyclic amides and other functional groups and allowed the obtention of non-classical N-carboxyalkyl derivatives for which the corresponding chloroformates are not accessible or commercially available. The model reaction was successfully performed with car diesel engine emissions and opens the way for new perspectives of carbon capture and use solutions.Lire moins >
Lire la suite >A clean, safe, and efficient method for the N-carboxyalkylation of lactams was designed and studied in the current report. This three-component coupling of the substrate, carbon dioxide and an alkyl halide, has been developed as a green alternative to phosgene and chloroformates, and takes place at ambient temperature and low pressure of CO2. This provided an improved protocol for the protection of cyclic amides and other functional groups and allowed the obtention of non-classical N-carboxyalkyl derivatives for which the corresponding chloroformates are not accessible or commercially available. The model reaction was successfully performed with car diesel engine emissions and opens the way for new perspectives of carbon capture and use solutions.Lire moins >
Langue :
Anglais
Vulgarisation :
Non
Collections :
Source :