Solid state NMR: A powerful tool for the ...
Type de document :
Article dans une revue scientifique: Article original
URL permanente :
Titre :
Solid state NMR: A powerful tool for the characterization of borophosphate glasses
Auteur(s) :
Tricot, Grégory [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Alpysbay, Lazzat [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
Doumert, Bertrand [Auteur]
Institut Michel Eugène Chevreul - FR 2638 [IMEC]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Alpysbay, Lazzat [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
Doumert, Bertrand [Auteur]
Institut Michel Eugène Chevreul - FR 2638 [IMEC]
Titre de la revue :
Molecules
Numéro :
25
Date de publication :
2020
Discipline(s) HAL :
Planète et Univers [physics]/Sciences de la Terre
Résumé en anglais : [en]
This review will show how solid state nuclear magnetic resonance (NMR) has contributed to a better understanding of the borophosphate glass structure. Over the last fifteen years, 1D and 2D magic angle spinning (MAS)-NMR ...
Lire la suite >This review will show how solid state nuclear magnetic resonance (NMR) has contributed to a better understanding of the borophosphate glass structure. Over the last fifteen years, 1D and 2D magic angle spinning (MAS)-NMR has been used to produce key information about both local and medium range organization in this type of glass. After a brief presentation on borophosphate glasses, the paper will focus on the description of the local order of phosphate and borate species obtained by 1D P-31-and B-11-MAS-NMR experiments, with a special emphasis on the improvements obtained at high magnetic fields on the borate speciation description. The last part of this review will show how correlation NMR provided new insights into the intermediate length scale order. Special attention will be paid to the quantitative data retrieved from B-11/P-31 REDOR-based NMR sequences and to the qualitative connectivity schemes observed on the 2D B-11/P-31 maps edited with the heteronuclear multiple quantum coherence (HMQC) NMR techniques.Lire moins >
Lire la suite >This review will show how solid state nuclear magnetic resonance (NMR) has contributed to a better understanding of the borophosphate glass structure. Over the last fifteen years, 1D and 2D magic angle spinning (MAS)-NMR has been used to produce key information about both local and medium range organization in this type of glass. After a brief presentation on borophosphate glasses, the paper will focus on the description of the local order of phosphate and borate species obtained by 1D P-31-and B-11-MAS-NMR experiments, with a special emphasis on the improvements obtained at high magnetic fields on the borate speciation description. The last part of this review will show how correlation NMR provided new insights into the intermediate length scale order. Special attention will be paid to the quantitative data retrieved from B-11/P-31 REDOR-based NMR sequences and to the qualitative connectivity schemes observed on the 2D B-11/P-31 maps edited with the heteronuclear multiple quantum coherence (HMQC) NMR techniques.Lire moins >
Audience :
Non spécifiée
Vulgarisation :
Non
Établissement(s) :
ENSCL
CNRS
Université de Lille
CNRS
Université de Lille
Collections :
Équipe(s) de recherche :
Propriétés magnéto structurales des matériaux (PMSM)
Date de dépôt :
2024-02-21T17:11:53Z
2024-02-23T11:19:51Z
2024-02-23T11:44:24Z
2024-02-23T11:19:51Z
2024-02-23T11:44:24Z
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- molecules-25-00428-v2.pdf
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