Strategies to improve hydrogen activation ...
Type de document :
Article dans une revue scientifique: Article de synthèse/Review paper
PMID :
URL permanente :
Titre :
Strategies to improve hydrogen activation on gold catalysts
Auteur(s) :
Dimitratos, Nikolaos [Auteur]
Alma Mater Studiorum Università di Bologna = University of Bologna [UNIBO]
Vilé, Gianvito [Auteur]
Politecnico di Milano [Milan] [POLIMI]
Albonetti, Stefania [Auteur]
Alma Mater Studiorum Università di Bologna = University of Bologna [UNIBO]
Cavani, Fabrizio [Auteur]
Alma Mater Studiorum Università di Bologna = University of Bologna [UNIBO]
Fiorio, Jhonatan [Auteur]
Technische Universität Dresden = Dresden University of Technology [TU Dresden]
López, Núria [Auteur]
Institute of Chemical Research of Catalonia [ICIQ]
Rossi, Liane M. [Auteur]
Universidade de São Paulo = University of São Paulo [USP]
Wojcieszak, Robert [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Alma Mater Studiorum Università di Bologna = University of Bologna [UNIBO]
Vilé, Gianvito [Auteur]
Politecnico di Milano [Milan] [POLIMI]
Albonetti, Stefania [Auteur]
Alma Mater Studiorum Università di Bologna = University of Bologna [UNIBO]
Cavani, Fabrizio [Auteur]
Alma Mater Studiorum Università di Bologna = University of Bologna [UNIBO]
Fiorio, Jhonatan [Auteur]
Technische Universität Dresden = Dresden University of Technology [TU Dresden]
López, Núria [Auteur]
Institute of Chemical Research of Catalonia [ICIQ]
Rossi, Liane M. [Auteur]
Universidade de São Paulo = University of São Paulo [USP]
Wojcieszak, Robert [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Titre de la revue :
Nature Reviews Chemistry
Nom court de la revue :
Nat Rev Chem
Numéro :
8
Pagination :
195–210
Éditeur :
Nature Publishing Group
Date de publication :
2024-02-23
ISSN :
2397-3358
Mot(s)-clé(s) en anglais :
Density functional theory
Heterogeneous catalysis
Heterogeneous catalysis
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
Catalytic reactions involving molecular hydrogen are at the heart of many transformations in the chemical industry. Classically, hydrogenations are carried out on Pd, Pt, Ru or Ni catalysts. However, the use of supported ...
Lire la suite >Catalytic reactions involving molecular hydrogen are at the heart of many transformations in the chemical industry. Classically, hydrogenations are carried out on Pd, Pt, Ru or Ni catalysts. However, the use of supported Au catalysts has garnered attention in recent years owing to their exceptional selectivity in hydrogenation reactions. This is despite the limited understanding of the physicochemical aspects of hydrogen activation and reaction on Au surfaces. A rational design of new improved catalysts relies on making better use of the hydrogenating properties of Au. This Review analyses the strategies utilized to improve hydrogen–Au interactions, from addressing the importance of the Au particle size to exploring alternative mechanisms for H2 dissociation on Au cations and Au–ligand interfaces. These insights hold the potential to drive future applications of Au catalysis.Lire moins >
Lire la suite >Catalytic reactions involving molecular hydrogen are at the heart of many transformations in the chemical industry. Classically, hydrogenations are carried out on Pd, Pt, Ru or Ni catalysts. However, the use of supported Au catalysts has garnered attention in recent years owing to their exceptional selectivity in hydrogenation reactions. This is despite the limited understanding of the physicochemical aspects of hydrogen activation and reaction on Au surfaces. A rational design of new improved catalysts relies on making better use of the hydrogenating properties of Au. This Review analyses the strategies utilized to improve hydrogen–Au interactions, from addressing the importance of the Au particle size to exploring alternative mechanisms for H2 dissociation on Au cations and Au–ligand interfaces. These insights hold the potential to drive future applications of Au catalysis.Lire moins >
Langue :
Anglais
Comité de lecture :
Oui
Audience :
Internationale
Vulgarisation :
Non
Projet ANR :
Établissement(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Équipe(s) de recherche :
Valorisation des alcanes et de la biomasse (VAALBIO)
Date de dépôt :
2024-02-29T00:03:03Z
2024-03-08T08:37:29Z
2024-03-08T08:37:29Z