Improved Hydrotropic Extraction of Carnosic ...
Type de document :
Article dans une revue scientifique
URL permanente :
Titre :
Improved Hydrotropic Extraction of Carnosic Acid from Rosemary and Sage with Short-Chain Monoalkyl Glycerol Ethers
Auteur(s) :
Mazaud, Agathe [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Lebeuf, Raphael [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Laguerre, Mickaël [Auteur]
Nardello-Rataj, Véronique [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Lebeuf, Raphael [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Laguerre, Mickaël [Auteur]
Nardello-Rataj, Véronique [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Titre de la revue :
ACS Sustainable Chemistry & Engineering
Nom court de la revue :
ACS Sustainable Chem. Eng.
Numéro :
10
Pagination :
3673-3681
Éditeur :
American Chemical Society (ACS)
Date de publication :
2022-03-10
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
Hydrotropic extraction in water with biobased amphiphiles is considered as an interesting alternative to conventional extraction with organic solvents. In this study, butyl, isoamyl, and pentyl glycerol ethers (C4Gly, ...
Lire la suite >Hydrotropic extraction in water with biobased amphiphiles is considered as an interesting alternative to conventional extraction with organic solvents. In this study, butyl, isoamyl, and pentyl glycerol ethers (C4Gly, iC5Gly, and C5Gly, respectively) are investigated for the extraction from rosemary (Rosmarinus officinalis) and sage (Salvia officinalis) of carnosic acid (CA), a powerful natural antioxidant used as an alternative to synthetic ones in food and cosmetic industries. First, interactions between CA and hydrotropes are studied to set the extraction conditions, resulting in the measurement of the solubility curves and miscibility of CA in the hydrotropic solutions. Then, C5Gly is shown to have the highest efficiency to extract CA, which is rationalized with a molecular model previously established for an alkyl polyethylene glycol ether (CiEj) series of amphiphiles based on their log P and molecular volume. Additionally, measurement of the contact angles of the hydrotropic solutions on rosemary leaves indicates that the efficiency of the hydrotrope is also dependent on the interfacial tension.Lire moins >
Lire la suite >Hydrotropic extraction in water with biobased amphiphiles is considered as an interesting alternative to conventional extraction with organic solvents. In this study, butyl, isoamyl, and pentyl glycerol ethers (C4Gly, iC5Gly, and C5Gly, respectively) are investigated for the extraction from rosemary (Rosmarinus officinalis) and sage (Salvia officinalis) of carnosic acid (CA), a powerful natural antioxidant used as an alternative to synthetic ones in food and cosmetic industries. First, interactions between CA and hydrotropes are studied to set the extraction conditions, resulting in the measurement of the solubility curves and miscibility of CA in the hydrotropic solutions. Then, C5Gly is shown to have the highest efficiency to extract CA, which is rationalized with a molecular model previously established for an alkyl polyethylene glycol ether (CiEj) series of amphiphiles based on their log P and molecular volume. Additionally, measurement of the contact angles of the hydrotropic solutions on rosemary leaves indicates that the efficiency of the hydrotrope is also dependent on the interfacial tension.Lire moins >
Langue :
Anglais
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Équipe(s) de recherche :
Colloïdes catalyse oxydation (CÏSCO)
Date de dépôt :
2024-04-03T10:39:14Z