MOF‐derived Ni‐WxC/carbon catalysts: Application to cellulose conversion into glycols

Boulos, Joseph; Goc, Firat; Marinova, Maya; Perret, Noémie; Rataboul, Franck; Royer, sebastien; Dhainaut, Jérémy

Document type :

Article dans une revue scientifique: Article original

DOI :

10.1002/cctc.202400548

Permalink :

http://hdl.handle.net/20.500.12210/114947

Title :

MOF‐derived Ni‐WxC/carbon catalysts: Application to cellulose conversion into glycols

Author(s) :

Boulos, Joseph [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Goc, Firat [Auteur]
IRCELYON-C'Durable [CDURABLE]
Marinova, Maya [Auteur]

Institut Chevreul - FR2638
Perret, Noémie [Auteur]
IRCELYON-C'Durable [CDURABLE]
Rataboul, Franck [Auteur]
IRCELYON-C'Durable [CDURABLE]
Royer, sebastien [Auteur]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Dhainaut, Jérémy [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Journal title :

ChemCatChem

Abbreviated title :

ChemCatChem

Publisher :

Wiley

Publication date :

2024-06-04

ISSN :

1867-3899

English keyword(s) :

Metal-organic framewor
Hierarchical porosity
Cellulose
Hydrogenolysis
Bimetallic nanoparticles

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

In this work, a series of Ni‐WxC/carbon materials have been prepared from a MOF precursor, DUT‐8(Ni), following different tungsten deposition routes. After pyrolysis, nickel‐tungsten alloys and tungsten carbide phases over ...
Show more >In this work, a series of Ni‐WxC/carbon materials have been prepared from a MOF precursor, DUT‐8(Ni), following different tungsten deposition routes. After pyrolysis, nickel‐tungsten alloys and tungsten carbide phases over nitrogen‐doped carbons were obtained. These materials were applied to cellulose hydrogenolysis, where molar yields of up to 46% in ethylene glycol (EG) and 9% in propylene glycol (PG) were obtained at 245 °C after 1 hour of reaction time. The best performing catalyst demonstrated promising stability, as the EG yield remained constant over 3 recycling tests and very little nanoparticles sintering was observed.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

ANR Project :

Transformation de biomasse lignocellulosique en glycols et dérivés aminés : conception de catalyseurs, réactivité, modélisation

Administrative institution(s) :

Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois

Collections :

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Matériaux pour la catalyse (MATCAT)

Submission date :

2024-06-05T09:32:50Z
2024-06-07T06:42:29Z

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Version	Link	Modification date
2	20.500.12210/114947*	2024-06-07T06:36:35Z
1	20.500.12210/114947.1	2024-06-05T09:32:50Z

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MOF‐derived Ni‐WxC/carbon catalysts: ...

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