Title :

Nonconventional Three-Component Hierarchical Host–Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, γ-Cyclodextrin, and Dawson-type Polyoxometalate

Author(s) :

Moussawi, Mhamad Aly [Auteur]
Haouas, Mohamed [Auteur]
Floquet, Sébastien [Auteur]
Shepard, William E. [Auteur]
Abramov, Pavel A. [Auteur]
Sokolov, Maxim N. [Auteur]
Fedin, Vladimir P. [Auteur]
Cordier, Stéphane [Auteur]
Ponchel, Anne [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Monflier, Eric [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Marrot, Jérôme [Auteur]
Cadot, Emmanuel [Auteur]

Journal title :

Journal of the American Chemical Society

Volume number :

139

Pages :

14376-14379

Publisher :

ACS

Publication date :

2017-10-02

English keyword(s) :

Supramolecular structures and assemblies
Anions
Adducts
Noncovalent interactions
Cavities

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

In this communication, we report on a noteworthy hybrid supramolecular assembly built from three functional components hierarchically organized through noncovalent interactions. The one-pot synthesis procedure leads to the ...
Show more >In this communication, we report on a noteworthy hybrid supramolecular assembly built from three functional components hierarchically organized through noncovalent interactions. The one-pot synthesis procedure leads to the formation of large Mo-blue ring-shaped anion {Mo154}, which contains the supramolecular adduct based on the symmetric encapsulation of the Dawson-type [P2W18O62]6– anion by two γ-cyclodextrin units. Such a nanoscopic onion-like structure, noted [P2W18O62]@2γ-CD@{Mo154} has been characterized by single-crystal X-ray diffraction, thus demonstrating the capability of the giant inorganic torus to develop relevant supramolecular chemistry, probing the strong affinity of the inner and outer faces of the γ-CD for the polyoxometalate surfaces. Furthermore, interactions and behavior in solution have been studied by multinuclear NMR spectroscopy, which supports specific interactions between γ-CD and POM units. Finally, the formation of this three-component hybrid assembly from one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the driving forces orchestrating this highly efficient multilevel recognition process.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Other project(s) or funding source(s) :

LIA-CNRS CLUSPOM
LABEX CHARIVIMMAT
University of Versailles Saint Quentin
CNRS
Region Ile de France through DIM Nano K

Administrative institution(s) :

ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Catalyse et chimie supramoléculaire (CASU)

Submission date :

2019-09-25T14:05:52Z
2021-04-01T13:24:33Z