Rheological properties of wormlike micellar ...
Document type :
Article dans une revue scientifique
Permalink :
Title :
Rheological properties of wormlike micellar gels formed by novel bio-based isosorbide surfactants
Author(s) :
Kamada, Miho [Auteur]
Pierlot, Christel [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Molinier, Valérie [Auteur]
Aubry, Jean-Marie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Aramaki, Kenji [Auteur]
Pierlot, Christel [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Molinier, Valérie [Auteur]
Aubry, Jean-Marie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Aramaki, Kenji [Auteur]
Journal title :
Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume number :
536
Pages :
82-87
Publisher :
Elsevier
Publication date :
2018-01-05
English keyword(s) :
Wormlike micelle
Isosorbide
Viscoelasticity
Bio-based surfactant
Isomeric effect
Isosorbide
Viscoelasticity
Bio-based surfactant
Isomeric effect
HAL domain(s) :
Chimie/Chimie organique
English abstract : [en]
Utilization of renewable resources is gaining significance. Isosorbide, which is derived from corn, has been attracting attention as a basic component in various industrial applications. Isosorbide surfactants having an ...
Show more >Utilization of renewable resources is gaining significance. Isosorbide, which is derived from corn, has been attracting attention as a basic component in various industrial applications. Isosorbide surfactants having an isosorbide group as a building block are called bio-based surfactants. In this study, we report wormlike micelle formation with a mixed surfactant solution of sodium 5-O-dodecyl isosorbide sulfate (SDSS) and 2-O- or 5-O-dodecyl isosorbide (2-DS or 5-DS, respectively). We studied the viscosity behavior of the 3 wt%NaCl aq./SDSS system with 2-DS or 5-DS at a constant surfactant concentration (5 wt%). The maximum viscosity was achieved at the same surfactant mixing composition for both systems but was higher in the 5-DS system. We also studied the dynamic rheological behavior. Oscillatory-shear (frequency sweep) measurements were performed on the viscoelastic samples that were formed around the viscosity maximum composition. Liquid-like behavior (G′ < G′′) was observed in the low-frequency region, whereas solid-like behavior (G′ > G′′) was observed in the high-frequency region. The Maxwell-type oscillatory rheological behavior of viscous micellar solutions can be related to the transient network formed by the entanglement of wormlike micelles. The Maxwell model was also fitted to the data, indicating wormlike micelle formation. The mesh size for the 2-DS system (58 nm) was larger than that for the 5-DS system (47 nm) around the maximum viscosity. This suggests that the 2-DS system forms shorter wormlike micelles with SDSS than does the 5-DS system, because of the possible larger head group area of 2-DS in the SDSS-2-DS mixed layer. Therefore a higher maximum η0 was observed in the 5-DS system.Show less >
Show more >Utilization of renewable resources is gaining significance. Isosorbide, which is derived from corn, has been attracting attention as a basic component in various industrial applications. Isosorbide surfactants having an isosorbide group as a building block are called bio-based surfactants. In this study, we report wormlike micelle formation with a mixed surfactant solution of sodium 5-O-dodecyl isosorbide sulfate (SDSS) and 2-O- or 5-O-dodecyl isosorbide (2-DS or 5-DS, respectively). We studied the viscosity behavior of the 3 wt%NaCl aq./SDSS system with 2-DS or 5-DS at a constant surfactant concentration (5 wt%). The maximum viscosity was achieved at the same surfactant mixing composition for both systems but was higher in the 5-DS system. We also studied the dynamic rheological behavior. Oscillatory-shear (frequency sweep) measurements were performed on the viscoelastic samples that were formed around the viscosity maximum composition. Liquid-like behavior (G′ < G′′) was observed in the low-frequency region, whereas solid-like behavior (G′ > G′′) was observed in the high-frequency region. The Maxwell-type oscillatory rheological behavior of viscous micellar solutions can be related to the transient network formed by the entanglement of wormlike micelles. The Maxwell model was also fitted to the data, indicating wormlike micelle formation. The mesh size for the 2-DS system (58 nm) was larger than that for the 5-DS system (47 nm) around the maximum viscosity. This suggests that the 2-DS system forms shorter wormlike micelles with SDSS than does the 5-DS system, because of the possible larger head group area of 2-DS in the SDSS-2-DS mixed layer. Therefore a higher maximum η0 was observed in the 5-DS system.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Colloïdes catalyse oxydation (CÏSCO)
Submission date :
2019-09-25T14:37:47Z
2021-03-17T16:38:52Z
2021-03-17T16:38:52Z