Use of a distribution function of relaxation ...
Type de document :
Article dans une revue scientifique
URL permanente :
Titre :
Use of a distribution function of relaxation times (DFRT) in impedance analysis of SOFC electrodes
Auteur(s) :
Boukamp, Bernard A. [Auteur]
University of Twente
Rolle, Aurelie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Université de Lille
University of Twente
Rolle, Aurelie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Université de Lille
Titre de la revue :
Solid State Ionics
Numéro :
314
Pagination :
103-111
Éditeur :
Elsevier
Date de publication :
2018-01
Mot(s)-clé(s) en anglais :
Distribution function of relaxation times (DFRT)
Electrochemical Impedance Spectroscopy (EIS)
Finite Length Warburg (FLW)
Gerischer dispersion
Electrodes
Electrochemical Impedance Spectroscopy (EIS)
Finite Length Warburg (FLW)
Gerischer dispersion
Electrodes
Discipline(s) HAL :
Chimie/Chimie inorganique
Résumé en anglais : [en]
Electrochemical Impedance Spectroscopy (EIS) is a frequently used method to characterize electrodes for Solid Oxide Fuel Cells (SOFC) or Electrolyzer Cells (SOEC). The porous microstructures, use of composite structures ...
Lire la suite >Electrochemical Impedance Spectroscopy (EIS) is a frequently used method to characterize electrodes for Solid Oxide Fuel Cells (SOFC) or Electrolyzer Cells (SOEC). The porous microstructures, use of composite structures and sometimes extra functional layers in an electrode, result often in impedance spectra that are difficult to analyze. Transformation of the impedance into a distribution function of relaxation times (DFRT) is about to become a new standard in EIS analysis. This inversion to the τ-domain requires solving a Fredholm integral of the second kind, which is known as an ‘ill-posed inverse problem’. Hence the resulting DFRT's should not be trusted directly. In cases were impedance data can be modelled satisfactory with an Equivalent Circuit (EqC), built of known dispersion relations (e.g. (RQ), Gerischer, Finite Length Warburg) an analytic distribution function, G(τ), can be constructed. This can be compared with the inversion results obtained from Fourier Transform (FT), Tikhonov Regularization (TR) and multi-(RQ) CNLS fits (m(RQ)fit), thus allowing evaluation and validation of these methods This is illustrated in this contribution with four examples of SOFC cathodes with quite different properties. The results apply equally well to SOFC anodes (or SOEC cathodes).Lire moins >
Lire la suite >Electrochemical Impedance Spectroscopy (EIS) is a frequently used method to characterize electrodes for Solid Oxide Fuel Cells (SOFC) or Electrolyzer Cells (SOEC). The porous microstructures, use of composite structures and sometimes extra functional layers in an electrode, result often in impedance spectra that are difficult to analyze. Transformation of the impedance into a distribution function of relaxation times (DFRT) is about to become a new standard in EIS analysis. This inversion to the τ-domain requires solving a Fredholm integral of the second kind, which is known as an ‘ill-posed inverse problem’. Hence the resulting DFRT's should not be trusted directly. In cases were impedance data can be modelled satisfactory with an Equivalent Circuit (EqC), built of known dispersion relations (e.g. (RQ), Gerischer, Finite Length Warburg) an analytic distribution function, G(τ), can be constructed. This can be compared with the inversion results obtained from Fourier Transform (FT), Tikhonov Regularization (TR) and multi-(RQ) CNLS fits (m(RQ)fit), thus allowing evaluation and validation of these methods This is illustrated in this contribution with four examples of SOFC cathodes with quite different properties. The results apply equally well to SOFC anodes (or SOEC cathodes).Lire moins >
Langue :
Anglais
Comité de lecture :
Oui
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Université de Lille
Collections :
Équipe(s) de recherche :
Matériaux inorganiques, structures, systèmes et propriétés (MISSP)
Date de dépôt :
2019-09-25T15:07:12Z
2021-03-04T10:12:30Z
2021-03-04T10:12:30Z