Airplane Soot Chemical Composition Analysis ...
Document type :
Communication dans un congrès avec actes
Title :
Airplane Soot Chemical Composition Analysis by Laser Desorption and Secondary Ions Mass Spectrometry
Author(s) :
Irimea, C. [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Ortega, I.K. [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Carpentier, Y. [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Ziskind, Michael [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Ouf, F.X. [Auteur]
Institut de Radioprotection et de Sûreté Nucléaire [IRSN]
Salm, F. [Auteur]
Institut de Radioprotection et de Sûreté Nucléaire [IRSN]
Delhaye, D. [Auteur]
ONERA - The French Aerospace Lab [Palaiseau]
Gaffié, D. [Auteur]
ONERA - The French Aerospace Lab [Palaiseau]
Faccinetto, Alessandro [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Focsa, Cristian [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Ortega, I.K. [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Carpentier, Y. [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Ziskind, Michael [Auteur]

Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Ouf, F.X. [Auteur]
Institut de Radioprotection et de Sûreté Nucléaire [IRSN]
Salm, F. [Auteur]
Institut de Radioprotection et de Sûreté Nucléaire [IRSN]
Delhaye, D. [Auteur]
ONERA - The French Aerospace Lab [Palaiseau]
Gaffié, D. [Auteur]
ONERA - The French Aerospace Lab [Palaiseau]
Faccinetto, Alessandro [Auteur]

Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Focsa, Cristian [Auteur]

Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Conference title :
2014 International Aerosol Conference
City :
Busan
Country :
Corée du Sud
Start date of the conference :
2014-08-28
Keyword(s) :
SOOT
PAH
AVIATION
LASER DESORPTION
SIMS
PAH
AVIATION
LASER DESORPTION
SIMS
HAL domain(s) :
Sciences de l'ingénieur [physics]/Milieux fluides et réactifs
English abstract : [en]
The present work has been performed in the framework of the French national project MERMOSE, which aims to characterize the soot emissions from airplane engines and to determine their role in the formation of cirrus clouds. ...
Show more >The present work has been performed in the framework of the French national project MERMOSE, which aims to characterize the soot emissions from airplane engines and to determine their role in the formation of cirrus clouds. A first sampling campaign performed on the PowerJet SaM-146 turbofan (SNECMA/Saturn) provided soot particles collected on quartz fiber filters in four engine regimes (30 %, 70 %, 85 % and 100 %). Two-Step (Desorption/Ionization) Laser Mass Spectrometry (L2MS) and Time of Fight Secondary Ion Mass Spectrometry (ToF-SIMS) techniques were used to analyze the surface chemical composition of the soot particles, with special focus on PAHs. In L2MS, the adsorbed phase is probed by nanosecond laser desorption (532nm), then the ejected molecules are ionized with a second ns laser (266nm) and further mass-separated by ToF-MS.Show less >
Show more >The present work has been performed in the framework of the French national project MERMOSE, which aims to characterize the soot emissions from airplane engines and to determine their role in the formation of cirrus clouds. A first sampling campaign performed on the PowerJet SaM-146 turbofan (SNECMA/Saturn) provided soot particles collected on quartz fiber filters in four engine regimes (30 %, 70 %, 85 % and 100 %). Two-Step (Desorption/Ionization) Laser Mass Spectrometry (L2MS) and Time of Fight Secondary Ion Mass Spectrometry (ToF-SIMS) techniques were used to analyze the surface chemical composition of the soot particles, with special focus on PAHs. In L2MS, the adsorbed phase is probed by nanosecond laser desorption (532nm), then the ejected molecules are ionized with a second ns laser (266nm) and further mass-separated by ToF-MS.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Source :
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