Titre :

The salt-free nickel-catalysed alpha-allylation reaction of ketones with allyl alcohol and diallylether

Auteur(s) :

Mouhsine, Bouchaib [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Karim, Abdallah [Auteur]
Université Cadi Ayyad [Marrakech] [UCA]
Dumont, Clement [Auteur]
Institut Catholique d'Arts et Métiers [ICAM]
Sauthier, Mathieu [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Titre de la revue :

Green Chemistry

Nom court de la revue :

Green Chem.

Numéro :

22

Pagination :

950-955

Date de publication :

2020-02-07

ISSN :

1463-9262

Discipline(s) HAL :

Chimie/Catalyse

Résumé en anglais : [en]

The nickel-catalysed α-allylation of ketones with allyl alcohol and diallylether has been performed under neutral conditions. As no base is involved, the products are synthesized without salts as side products. The ...
Lire la suite >The nickel-catalysed α-allylation of ketones with allyl alcohol and diallylether has been performed under neutral conditions. As no base is involved, the products are synthesized without salts as side products. The dppf/Ni(cod)2 catalytic system in MeOH at 80 °C has been shown as the most effective reaction system to afford tetrasubstituted derivatives from various cyclic and acyclic ketones with one or two mobile protons. This process combined with a metathesis step yields spirocyclic compounds according to a salt free synthetic sequence.Lire moins >

Langue :

Anglais

Comité de lecture :

Oui

Audience :

Internationale

Vulgarisation :

Non

Établissement(s) :

CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Équipe(s) de recherche :

Catalyse et synthèse éco-compatible (CASECO)

Date de dépôt :

2022-03-02T07:13:03Z
2023-12-05T10:40:28Z