Title :

Effect of p/ni ratio on the performance of nickel phosphide phases supported on zirconia for the hydrodeoxygenation of m-cresol

Author(s) :

Goncalves, Vinicius Ottonio O. [Auteur]
Magalhaes De Souza, Priscilla [Auteur]
Cabioc''h, Thierry [Auteur]
Da Silva, Victor Teixeira [Auteur]
Bellot Noronha, Fabio [Auteur]
Richard, Frederic [Auteur]

Journal title :

Catalysis Communications

Abbreviated title :

Catal. Commun.

Volume number :

119

Pages :

33-38

Publication date :

2019-01-10

ISSN :

1566-7367

English keyword(s) :

Nickel phosphide catalysts
ZrO2
Ni2P
Ni12P5
HDO
m-cresol

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

The catalytic performances of various nickel phosphide catalysts (NiP) supported on ZrO2 synthesized with different P/Ni molar ratios (0.8, 2 and 3) were investigated in hydrodeoxygenation (HDO) of m-cresol at 340 °C under ...
Show more >The catalytic performances of various nickel phosphide catalysts (NiP) supported on ZrO2 synthesized with different P/Ni molar ratios (0.8, 2 and 3) were investigated in hydrodeoxygenation (HDO) of m-cresol at 340 °C under 4 MPa. The solid sample with the highest P/Ni ratio (NiP-3/ZrO2) presented the best catalytic performances in terms of activity, which were attributed to the presence of the pure Ni2P phase, the other samples containing either a mixture of Ni2P and Ni12P5 (NiP-2/ZrO2) or Ni12P5 (NiP-0.8/ZrO2) alone were less active. The use of ZrO2 as support required a large excess of P to obtain Ni2P as active phase.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Valorisation des alcanes et de la biomasse (VAALBIO)

Submission date :

2022-03-02T07:13:44Z