Title :

Bifunctional homogeneous catalysts based on first row transition metals in asymmetric hydrogenation

Author(s) :

Agbossou-Niedercorn, Francine [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Michon, Christophe [Auteur]
Unité de Catalyse et de Chimie du Solide (UCCS) - UMR 8181

Journal title :

Coordination Chemistry Reviews

Abbreviated title :

Coord. Chem. Rev.

Volume number :

425

Publication date :

2020-12-15

ISSN :

0010-8545

Keyword(s) :

Cobalt
Nickel
Manganese
Iron
Bifunctional catalyst
Asymmetric hydrogenation

HAL domain(s) :

Chimie/Chimie de coordination

English abstract : [en]

This article reviews over the past 10 years the development of bifunctional homogeneous catalysts based on first row transition metals for asymmetric hydrogenation of various CC, CO and CN double bonds. Following the ...
Show more >This article reviews over the past 10 years the development of bifunctional homogeneous catalysts based on first row transition metals for asymmetric hydrogenation of various CC, CO and CN double bonds. Following the impressive performances of ruthenium based bifunctional catalysts in asymmetric transfer hydrogenation and asymmetric hydrogenation and, because of economic, environmental and societal reasons, bifunctional catalysts based on abundant metals and mainly on the first row transition metals have gradually been developed over the last decade. Hence, several bifunctional catalysts based on iron, manganese, cobalt and nickel have been reported and promising activities and enantioselectivities have already been achieved. This review highlights and discusses the reactivity and performances of these new bifunctional catalysts as well as the implied reaction mechanisms.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Méthodologie organométallique pour la catalyse homogène (MOCAH)

Submission date :

2022-03-02T07:15:02Z
2024-01-15T16:12:20Z