Catalytic Production of Glycolic Acid from ...
Type de document :
Article dans une revue scientifique: Article original
DOI :
URL permanente :
Titre :
Catalytic Production of Glycolic Acid from Glycerol Oxidation: An Optimization Using Response Surface Methodology
Auteur(s) :
Tavera Ruiz, Claudia Patricia [Auteur]
Ecole Nationale Supérieure de Chimie de Lille [ENSCL]
Dumeignil, Franck [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Capron, Mickael [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Ecole Nationale Supérieure de Chimie de Lille [ENSCL]
Dumeignil, Franck [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Capron, Mickael [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Titre de la revue :
Catalysts
Nom court de la revue :
Catalysts
Numéro :
11
Pagination :
257
Éditeur :
MDPI
Date de publication :
2021-02-15
ISSN :
2073-4344
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
This study aimed at optimizing the production of glycolic acid from glycerol catalytic oxidation over a silver catalyst supported on a mixed cerium-zirconium oxide, to progress towards the industrialization of a derived ...
Lire la suite >This study aimed at optimizing the production of glycolic acid from glycerol catalytic oxidation over a silver catalyst supported on a mixed cerium-zirconium oxide, to progress towards the industrialization of a derived process. Optimization of the operating conditions was performed using the response surface methodology. We concluded that the production of glycolic acid depends mainly of glycerol concentration, NaOH/glycerol ratio, catalyst/glycerol ratio, and O2/glycerol ratio. The optimal conditions we found were a temperature of 60 °C, a NaOH/glycerol molar ratio of 2, an O2/glycerol molar ratio of 0.23, and a catalyst/glycerol mass ratio of 0.07. With these optimal conditions, it was possible to increase the glycerol concentration from 0.3 M to 2 M, obtaining an increase in the concentration of glycolic acid in the liquid fraction, from 0.27 mol/L of glycolic acid (with initial glycerol solution 0.3 M) to 0.88 mol/L (with initial solution 2 M), while keeping a 100% glycerol conversion.Lire moins >
Lire la suite >This study aimed at optimizing the production of glycolic acid from glycerol catalytic oxidation over a silver catalyst supported on a mixed cerium-zirconium oxide, to progress towards the industrialization of a derived process. Optimization of the operating conditions was performed using the response surface methodology. We concluded that the production of glycolic acid depends mainly of glycerol concentration, NaOH/glycerol ratio, catalyst/glycerol ratio, and O2/glycerol ratio. The optimal conditions we found were a temperature of 60 °C, a NaOH/glycerol molar ratio of 2, an O2/glycerol molar ratio of 0.23, and a catalyst/glycerol mass ratio of 0.07. With these optimal conditions, it was possible to increase the glycerol concentration from 0.3 M to 2 M, obtaining an increase in the concentration of glycolic acid in the liquid fraction, from 0.27 mol/L of glycolic acid (with initial glycerol solution 0.3 M) to 0.88 mol/L (with initial solution 2 M), while keeping a 100% glycerol conversion.Lire moins >
Langue :
Anglais
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Collections :
Équipe(s) de recherche :
Valorisation des alcanes et de la biomasse (VAALBIO)
Date de dépôt :
2022-03-24T09:02:47Z
2023-01-11T10:31:20Z
2023-01-11T10:31:20Z
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