Isobaric Vapor–Liquid Equilibrium Data for ...
Document type :
Article dans une revue scientifique: Article original
DOI :
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Title :
Isobaric Vapor–Liquid Equilibrium Data for Six Binary Systems: Prop-2-en-1-ol (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–Hexan-2-one (2), Hexan-2-one (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-one (2), and 4-Methyl-pentan-2-one (1)–4-Methyl-pentan-2-ol (2) at 101.32 kPa
Author(s) :
Silva, Karen [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Katryniok, Benjamin [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Araque Marin, Marcia Carolina [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Katryniok, Benjamin [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Araque Marin, Marcia Carolina [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Journal title :
Journal of Chemical and Engineering Data
Abbreviated title :
J. Chem. Eng. Data
Volume number :
66
Pages :
1055-1067
Publication date :
2021-02-02
ISSN :
0021-9568, 1520-5134
HAL domain(s) :
Chimie/Catalyse
English abstract : [en]
In this work, isobaric vapor–liquid equilibrium (VLE) measurements were conducted for the binary systems of prop-2-en-1-ol (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–hexan-2-one (2), hexan-2-one (1)–hexan-2-ol (2), prop-2-en-1-ol ...
Show more >In this work, isobaric vapor–liquid equilibrium (VLE) measurements were conducted for the binary systems of prop-2-en-1-ol (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–hexan-2-one (2), hexan-2-one (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-one (2), and 4-methyl-pentan-2-one (1)–4-methyl-pentan-2-ol (2) to assist with the design of the separation process by distillation. Measurements were determined using Fischer VLE 602 equipment at 101.32 kPa. The thermodynamic consistency of the measured VLE data was validated by modified Herington, Van Ness, pure component consistency, and Redlich–Kister total area tests. Moreover, data sets were correlated using the nonrandom two-liquid (NRTL), universal quasichemical (UNIQUAC), and Wilson thermodynamic models to obtain the binary interaction parameters using the Aspen Plus V11 commercial software. The root-mean-square deviations (RMSDs) of the equilibrium temperature (T) and the vapor mole fraction (yi) were less than 0.24 and 0.0089, respectively, which indicate that these three thermodynamic models can be used to correlate the six binary systems and therefore they can be employed for the development and optimization of the separation process.Show less >
Show more >In this work, isobaric vapor–liquid equilibrium (VLE) measurements were conducted for the binary systems of prop-2-en-1-ol (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–hexan-2-one (2), hexan-2-one (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-one (2), and 4-methyl-pentan-2-one (1)–4-methyl-pentan-2-ol (2) to assist with the design of the separation process by distillation. Measurements were determined using Fischer VLE 602 equipment at 101.32 kPa. The thermodynamic consistency of the measured VLE data was validated by modified Herington, Van Ness, pure component consistency, and Redlich–Kister total area tests. Moreover, data sets were correlated using the nonrandom two-liquid (NRTL), universal quasichemical (UNIQUAC), and Wilson thermodynamic models to obtain the binary interaction parameters using the Aspen Plus V11 commercial software. The root-mean-square deviations (RMSDs) of the equilibrium temperature (T) and the vapor mole fraction (yi) were less than 0.24 and 0.0089, respectively, which indicate that these three thermodynamic models can be used to correlate the six binary systems and therefore they can be employed for the development and optimization of the separation process.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Valorisation des alcanes et de la biomasse (VAALBIO)
Submission date :
2022-03-24T09:02:59Z
2024-02-20T10:48:06Z
2024-02-20T10:48:06Z
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