Isobaric Vapor–Liquid Equilibrium Data for ...
Type de document :
Article dans une revue scientifique: Article original
DOI :
URL permanente :
Titre :
Isobaric Vapor–Liquid Equilibrium Data for Six Binary Systems: Prop-2-en-1-ol (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–Hexan-2-one (2), Hexan-2-one (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-one (2), and 4-Methyl-pentan-2-one (1)–4-Methyl-pentan-2-ol (2) at 101.32 kPa
Auteur(s) :
Silva, Karen [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Katryniok, Benjamin [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Araque Marin, Marcia Carolina [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Katryniok, Benjamin [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Araque Marin, Marcia Carolina [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Titre de la revue :
Journal of Chemical and Engineering Data
Nom court de la revue :
J. Chem. Eng. Data
Numéro :
66
Pagination :
1055-1067
Date de publication :
2021-02-02
ISSN :
0021-9568, 1520-5134
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
In this work, isobaric vapor–liquid equilibrium (VLE) measurements were conducted for the binary systems of prop-2-en-1-ol (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–hexan-2-one (2), hexan-2-one (1)–hexan-2-ol (2), prop-2-en-1-ol ...
Lire la suite >In this work, isobaric vapor–liquid equilibrium (VLE) measurements were conducted for the binary systems of prop-2-en-1-ol (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–hexan-2-one (2), hexan-2-one (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-one (2), and 4-methyl-pentan-2-one (1)–4-methyl-pentan-2-ol (2) to assist with the design of the separation process by distillation. Measurements were determined using Fischer VLE 602 equipment at 101.32 kPa. The thermodynamic consistency of the measured VLE data was validated by modified Herington, Van Ness, pure component consistency, and Redlich–Kister total area tests. Moreover, data sets were correlated using the nonrandom two-liquid (NRTL), universal quasichemical (UNIQUAC), and Wilson thermodynamic models to obtain the binary interaction parameters using the Aspen Plus V11 commercial software. The root-mean-square deviations (RMSDs) of the equilibrium temperature (T) and the vapor mole fraction (yi) were less than 0.24 and 0.0089, respectively, which indicate that these three thermodynamic models can be used to correlate the six binary systems and therefore they can be employed for the development and optimization of the separation process.Lire moins >
Lire la suite >In this work, isobaric vapor–liquid equilibrium (VLE) measurements were conducted for the binary systems of prop-2-en-1-ol (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–hexan-2-one (2), hexan-2-one (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-one (2), and 4-methyl-pentan-2-one (1)–4-methyl-pentan-2-ol (2) to assist with the design of the separation process by distillation. Measurements were determined using Fischer VLE 602 equipment at 101.32 kPa. The thermodynamic consistency of the measured VLE data was validated by modified Herington, Van Ness, pure component consistency, and Redlich–Kister total area tests. Moreover, data sets were correlated using the nonrandom two-liquid (NRTL), universal quasichemical (UNIQUAC), and Wilson thermodynamic models to obtain the binary interaction parameters using the Aspen Plus V11 commercial software. The root-mean-square deviations (RMSDs) of the equilibrium temperature (T) and the vapor mole fraction (yi) were less than 0.24 and 0.0089, respectively, which indicate that these three thermodynamic models can be used to correlate the six binary systems and therefore they can be employed for the development and optimization of the separation process.Lire moins >
Langue :
Anglais
Comité de lecture :
Oui
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Collections :
Équipe(s) de recherche :
Valorisation des alcanes et de la biomasse (VAALBIO)
Date de dépôt :
2022-03-24T09:02:59Z
2024-02-20T10:48:06Z
2024-02-20T10:48:06Z
Fichiers
- Article-2- EVL-Final version.pdf
- Version finale acceptée pour publication (postprint)
- Accès libre
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