Nanostructured BaTi(1-x)Sn(x)O(3 )ferroelectric ...
Document type :
Article dans une revue scientifique: Article original
Permalink :
Title :
Nanostructured BaTi(1-x)Sn(x)O(3 )ferroelectric materials for electrocaloric applications and energy performance
Author(s) :
Benyoussef, M. [Auteur]
Mura, T. [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
1066418|||UCCS Équipe Couches Minces & Nanomatériaux
Saitzek, Sebastien [Auteur]
UCCS Équipe Couches Minces & Nanomatériaux
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Azrour, F. [Auteur]
Blach, Jean-Francois [Auteur]
UCCS Équipe Couches Minces & Nanomatériaux
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Lahmar, A. [Auteur]
Gagou, Y. [Auteur]
El Marssi, M. [Auteur]
SAYEDE, Adlane [Auteur]
UCCS Équipe Couches Minces & Nanomatériaux
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Jouiad, M. [Auteur]
Mura, T. [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
1066418|||UCCS Équipe Couches Minces & Nanomatériaux
Saitzek, Sebastien [Auteur]

UCCS Équipe Couches Minces & Nanomatériaux
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Azrour, F. [Auteur]
Blach, Jean-Francois [Auteur]

UCCS Équipe Couches Minces & Nanomatériaux
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Lahmar, A. [Auteur]
Gagou, Y. [Auteur]
El Marssi, M. [Auteur]
SAYEDE, Adlane [Auteur]

UCCS Équipe Couches Minces & Nanomatériaux
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Jouiad, M. [Auteur]
Journal title :
Current Applied Physics
Volume number :
38
Pages :
59-66
Publisher :
Elsevier
Publication date :
2022-06-24
ISSN :
1567-1739
English keyword(s) :
BaTi1-xSnxO3
Nanomaterials
Electrocaloric
Energy storage
Nanomaterials
Electrocaloric
Energy storage
HAL domain(s) :
Physique [physics]/Matière Condensée [cond-mat]
Chimie/Matériaux
Chimie/Chimie inorganique
Chimie/Matériaux
Chimie/Chimie inorganique
English abstract : [en]
Nanostructured BaTi1-xSnxO3 (x = 0, 0.05 & 0.075) were successfully synthesized using the modified Pechini processing method. The phase purity and symmetry were examined by X-ray diffraction and Raman spectroscopy. Tetragonal ...
Show more >Nanostructured BaTi1-xSnxO3 (x = 0, 0.05 & 0.075) were successfully synthesized using the modified Pechini processing method. The phase purity and symmetry were examined by X-ray diffraction and Raman spectroscopy. Tetragonal symmetry was obtained for BaTiO3 (BT) while orthorhombic symmetry for Sn doped BT. BT exhibits an up-shift of the Curie temperature towards high temperatures (TC = 139 °C). In contrast, a down-shift was recorded for Sn doped BT. Then, indirect electrocaloric (EC) adiabatic temperature change ΔT and the energy storage performances were determined based on ferroelectric hysteresis loops. Interestingly, large EC responsivity of ΔT/ΔE = 0.81 × 10−6 K m/V was obtained for the BT accompanied with a moderate stored energy of 23 mJ/cm3 but with a high energy efficiency of 67%. The incorporation of Sn in BT was found to broaden the EC responsivity and to improve the energy efficiency up to 90%, recorded for the 5% Sn doped BT.Show less >
Show more >Nanostructured BaTi1-xSnxO3 (x = 0, 0.05 & 0.075) were successfully synthesized using the modified Pechini processing method. The phase purity and symmetry were examined by X-ray diffraction and Raman spectroscopy. Tetragonal symmetry was obtained for BaTiO3 (BT) while orthorhombic symmetry for Sn doped BT. BT exhibits an up-shift of the Curie temperature towards high temperatures (TC = 139 °C). In contrast, a down-shift was recorded for Sn doped BT. Then, indirect electrocaloric (EC) adiabatic temperature change ΔT and the energy storage performances were determined based on ferroelectric hysteresis loops. Interestingly, large EC responsivity of ΔT/ΔE = 0.81 × 10−6 K m/V was obtained for the BT accompanied with a moderate stored energy of 23 mJ/cm3 but with a high energy efficiency of 67%. The incorporation of Sn in BT was found to broaden the EC responsivity and to improve the energy efficiency up to 90%, recorded for the 5% Sn doped BT.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Research team(s) :
Couches minces & nanomatériaux (CMNM)
Submission date :
2023-05-03T00:25:08Z
2023-05-12T10:39:17Z
2023-05-12T10:39:17Z