High-resolution N-14-edited H-1-C-13 ...
Document type :
Article dans une revue scientifique: Article original
PMID :
Permalink :
Title :
High-resolution N-14-edited H-1-C-13 correlation NMR experiment to study biological solids
Author(s) :
Amoureux, Jean-Paul [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Trebosc, Julien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Hu, Bingwen [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Halpern-Manners, Nicholas [Auteur]
University of California [UC]
Antonijevic, Sasa [Auteur]
University of California [UC]
Lawrence Berkeley National Laboratory [Berkeley] [LBNL]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Trebosc, Julien [Auteur]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Hu, Bingwen [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Halpern-Manners, Nicholas [Auteur]
University of California [UC]
Antonijevic, Sasa [Auteur]
University of California [UC]
Lawrence Berkeley National Laboratory [Berkeley] [LBNL]
Journal title :
Journal of Magnetic Resonance
Abbreviated title :
J. Magn. Reson.
Volume number :
194
Pages :
317-320
Publication date :
2008-10
ISSN :
1090-7807
English keyword(s) :
Solid-state NMR
Coherence transfer
2D correlation
Nitrogen-14
Amino acids
Coherence transfer
2D correlation
Nitrogen-14
Amino acids
HAL domain(s) :
Chimie
English abstract : [en]
It was recently shown that nuclear magnetic resonance (NMR) spectra of nitrogen-14 (spin I = 1) can be obtained by indirect detection via spin S = 1/2 nuclei in powders spinning at the magic angle. An increased number of ...
Show more >It was recently shown that nuclear magnetic resonance (NMR) spectra of nitrogen-14 (spin I = 1) can be obtained by indirect detection via spin S = 1/2 nuclei in powders spinning at the magic angle. An increased number of solid-state NMR methods are now available to tailor sequences for specific purposes, e.g., hetero-nuclear dipolar recoupling or homo-nuclear dipolar decoupling schemes. Here, we combine the latest recoupling and decoupling techniques to obtain high-resolution 1H–13C through-space correlation spectra, where only the correlation peaks of those carbons close to nitrogen nuclei are observed. The experiment is demonstrated on a 13C enriched l-histidine. HCl·H2O powder sample.Show less >
Show more >It was recently shown that nuclear magnetic resonance (NMR) spectra of nitrogen-14 (spin I = 1) can be obtained by indirect detection via spin S = 1/2 nuclei in powders spinning at the magic angle. An increased number of solid-state NMR methods are now available to tailor sequences for specific purposes, e.g., hetero-nuclear dipolar recoupling or homo-nuclear dipolar decoupling schemes. Here, we combine the latest recoupling and decoupling techniques to obtain high-resolution 1H–13C through-space correlation spectra, where only the correlation peaks of those carbons close to nitrogen nuclei are observed. The experiment is demonstrated on a 13C enriched l-histidine. HCl·H2O powder sample.Show less >
Language :
Anglais
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Research team(s) :
RMN et matériaux inorganiques (RM2I)
Submission date :
2023-05-30T18:11:58Z
2024-04-26T09:45:45Z
2024-04-26T09:45:45Z