Properties and structure of SnO−SiO2 and SnO−SnF2−SiO2 glasses

Suzuki, K.; Tricot, Grégory; Revel, Bertrand; Saitoh, Akira

Document type :

Article dans une revue scientifique: Article original

DOI :

10.1016/j.jnoncrysol.2019.119706

Permalink :

http://hdl.handle.net/20.500.12210/108859

Title :

Properties and structure of SnO−SiO2 and SnO−SnF2−SiO2 glasses

Author(s) :

Suzuki, K. [Auteur]
Ehime University [Matsuyama, Japon]
Tricot, Grégory [Auteur]

Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Revel, Bertrand [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
Saitoh, Akira [Auteur]
Ehime University [Matsuyama, Japon]

Journal title :

Journal of Non-Crystalline Solids

Volume number :

527

Publication date :

2020

HAL domain(s) :

Planète et Univers [physics]/Sciences de la Terre

English abstract : [en]

Binary SnO−SiO2 and ternary SnO−SnF2−SiO2 glasses are investigated as potential alternative to lead containing glasses for the development of optical components using polarization light. Optical and thermal properties ...
Show more >Binary SnO−SiO2 and ternary SnO−SnF2−SiO2 glasses are investigated as potential alternative to lead containing glasses for the development of optical components using polarization light. Optical and thermal properties (including very small photoelastic constant, PEC) are reported herein. A minimum value of PEC (–0.008 × 10−12 Pa−1) is measured at a wavelength of 632.8 nm for the binary glass containing 43.6 mol% of SnO. The ternary glasses with fluorine of 8 − 9 mol% provide a very small PEC (–0.039 × 10−12 Pa−1) and blue-shifted optical absorption edge for 47.0 mol% of SnO+SnF2. The local structure of the silicate glass is investigated by micro-Raman and 119Sn, 29Si, and 19F nuclear magnetic resonance spectroscopies. It turns out that the zero PEC glass possesses a discrete silicate structure with meta- and pyro-silicate units. The relationship between the zero photoelastic property and the silicate structure is discussed.Show less >

Audience :

Non spécifiée

Popular science :

Non

Collections :

Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516

Research team(s) :

Propriétés magnéto structurales des matériaux (PMSM)

Submission date :

2024-02-21T17:11:53Z
2024-02-23T10:48:49Z
2024-02-23T11:40:28Z

Version	Link	Modification date
3	20.500.12210/108859*	2024-02-23T11:39:57Z
2	20.500.12210/108859.2	2024-02-23T10:45:10Z
1	20.500.12210/108859.1	2024-02-21T17:11:53Z

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Properties and structure of SnO−SiO2 and ...

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