Solid state NMR: A powerful tool for the characterization of borophosphate glasses

Tricot, Grégory; Alpysbay, Lazzat; Doumert, Bertrand

Document type :

Article dans une revue scientifique: Article original

DOI :

10.3390/molecules25020428

Permalink :

http://hdl.handle.net/20.500.12210/108861

Title :

Solid state NMR: A powerful tool for the characterization of borophosphate glasses

Author(s) :

Tricot, Grégory [Auteur]

Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Alpysbay, Lazzat [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
Doumert, Bertrand [Auteur]
Institut Michel Eugène Chevreul - FR 2638 [IMEC]

Journal title :

Molecules

Volume number :

Publication date :

2020

HAL domain(s) :

Planète et Univers [physics]/Sciences de la Terre

English abstract : [en]

This review will show how solid state nuclear magnetic resonance (NMR) has contributed to a better understanding of the borophosphate glass structure. Over the last fifteen years, 1D and 2D magic angle spinning (MAS)-NMR ...
Show more >This review will show how solid state nuclear magnetic resonance (NMR) has contributed to a better understanding of the borophosphate glass structure. Over the last fifteen years, 1D and 2D magic angle spinning (MAS)-NMR has been used to produce key information about both local and medium range organization in this type of glass. After a brief presentation on borophosphate glasses, the paper will focus on the description of the local order of phosphate and borate species obtained by 1D P-31-and B-11-MAS-NMR experiments, with a special emphasis on the improvements obtained at high magnetic fields on the borate speciation description. The last part of this review will show how correlation NMR provided new insights into the intermediate length scale order. Special attention will be paid to the quantitative data retrieved from B-11/P-31 REDOR-based NMR sequences and to the qualitative connectivity schemes observed on the 2D B-11/P-31 maps edited with the heteronuclear multiple quantum coherence (HMQC) NMR techniques.Show less >

Audience :

Non spécifiée

Popular science :

Non

Administrative institution(s) :

ENSCL
CNRS
Université de Lille

Collections :

Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516

Research team(s) :

Propriétés magnéto structurales des matériaux (PMSM)

Submission date :

2024-02-21T17:11:53Z
2024-02-23T11:19:51Z
2024-02-23T11:44:24Z

Files

molecules-25-00428-v2.pdf
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Except where otherwise noted, this item's license is described as Attribution 3.0 United States

Version	Link	Modification date
3	20.500.12210/108861*	2024-02-23T11:44:03Z
2	20.500.12210/108861.2	2024-02-23T11:16:16Z
1	20.500.12210/108861.1	2024-02-21T17:11:53Z

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Solid state NMR: A powerful tool for the ...

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