MOF‐derived Ni‐WxC/carbon catalysts: ...
Type de document :
Article dans une revue scientifique: Article original
DOI :
URL permanente :
Titre :
MOF‐derived Ni‐WxC/carbon catalysts: Application to cellulose conversion into glycols
Auteur(s) :
Boulos, Joseph [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Goc, Firat [Auteur]
IRCELYON-C'Durable [CDURABLE]
Marinova, Maya [Auteur]
Institut Chevreul - FR2638
Perret, Noémie [Auteur]
IRCELYON-C'Durable [CDURABLE]
Rataboul, Franck [Auteur]
IRCELYON-C'Durable [CDURABLE]
Royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Dhainaut, Jérémy [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Goc, Firat [Auteur]
IRCELYON-C'Durable [CDURABLE]
Marinova, Maya [Auteur]
Institut Chevreul - FR2638
Perret, Noémie [Auteur]
IRCELYON-C'Durable [CDURABLE]
Rataboul, Franck [Auteur]
IRCELYON-C'Durable [CDURABLE]
Royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Dhainaut, Jérémy [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Titre de la revue :
ChemCatChem
Nom court de la revue :
ChemCatChem
Éditeur :
Wiley
Date de publication :
2024-06-04
ISSN :
1867-3899
Mot(s)-clé(s) en anglais :
Metal-organic framewor
Hierarchical porosity
Cellulose
Hydrogenolysis
Bimetallic nanoparticles
Hierarchical porosity
Cellulose
Hydrogenolysis
Bimetallic nanoparticles
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
In this work, a series of Ni‐WxC/carbon materials have been prepared from a MOF precursor, DUT‐8(Ni), following different tungsten deposition routes. After pyrolysis, nickel‐tungsten alloys and tungsten carbide phases over ...
Lire la suite >In this work, a series of Ni‐WxC/carbon materials have been prepared from a MOF precursor, DUT‐8(Ni), following different tungsten deposition routes. After pyrolysis, nickel‐tungsten alloys and tungsten carbide phases over nitrogen‐doped carbons were obtained. These materials were applied to cellulose hydrogenolysis, where molar yields of up to 46% in ethylene glycol (EG) and 9% in propylene glycol (PG) were obtained at 245 °C after 1 hour of reaction time. The best performing catalyst demonstrated promising stability, as the EG yield remained constant over 3 recycling tests and very little nanoparticles sintering was observed.Lire moins >
Lire la suite >In this work, a series of Ni‐WxC/carbon materials have been prepared from a MOF precursor, DUT‐8(Ni), following different tungsten deposition routes. After pyrolysis, nickel‐tungsten alloys and tungsten carbide phases over nitrogen‐doped carbons were obtained. These materials were applied to cellulose hydrogenolysis, where molar yields of up to 46% in ethylene glycol (EG) and 9% in propylene glycol (PG) were obtained at 245 °C after 1 hour of reaction time. The best performing catalyst demonstrated promising stability, as the EG yield remained constant over 3 recycling tests and very little nanoparticles sintering was observed.Lire moins >
Langue :
Anglais
Comité de lecture :
Oui
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Équipe(s) de recherche :
Matériaux pour la catalyse (MATCAT)
Date de dépôt :
2024-06-05T09:32:50Z
2024-06-07T06:42:29Z
2024-06-07T06:42:29Z
Fichiers
- Accepted Article.pdf
- Version finale acceptée pour publication (postprint)
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