Cone–Plate Rheometer as Reactor and Viscosity ...
Document type :
Article dans une revue scientifique
DOI :
Permalink :
Title :
Cone–Plate Rheometer as Reactor and Viscosity Probe for the Detection of Transitional Phase Inversion of Brij30–Isopropyl Myristate–Water Model Emulsion
Author(s) :
Pierlot, Christel [Auteur]
Ontiveros, Jesus [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Catté, Marianne [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Salager, Jean-Louis [Auteur]
Aubry, Jean-Marie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Ontiveros, Jesus [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Catté, Marianne [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Salager, Jean-Louis [Auteur]
Aubry, Jean-Marie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Journal title :
Industrial & Engineering Chemistry Research
Volume number :
55
Pages :
3990-3999
Publication date :
2016-03-21
HAL domain(s) :
Chimie/Chimie organique
English abstract : [en]
Brij30/isopropyl myristate/water model emulsions were used to study the inversion morphology change from O/W to W/O. The transitional phase inversion was detected by monitoring the electrical conductivity during a ...
Show more >Brij30/isopropyl myristate/water model emulsions were used to study the inversion morphology change from O/W to W/O. The transitional phase inversion was detected by monitoring the electrical conductivity during a heating–cooling cycle while the viscosity of the emulsion was followed under constant shear rate with a cone–plate rheometer equipment. The two methods provide similar values of phase inversion temperature. However, different rheological profiles are observed depending on the surfactant concentration and water fraction. Viscosity maps of formulation-composition maps (specifically temperature–surfactant concentration and temperature–water fraction) pointed to the occurrence of both transitional and catastrophic inversion processes. A complete formulation–composition map with all different emulsion morphologies and isoviscosities contours for the 9% Brij30/IPM/water is presented. The use of a commercial cone–plate rheometer exhibits several advantages over the classical conductivity measurement; in particular, it does not imply any electrolyte addition in the aqueous phase and requires only a small volume of emulsion.Show less >
Show more >Brij30/isopropyl myristate/water model emulsions were used to study the inversion morphology change from O/W to W/O. The transitional phase inversion was detected by monitoring the electrical conductivity during a heating–cooling cycle while the viscosity of the emulsion was followed under constant shear rate with a cone–plate rheometer equipment. The two methods provide similar values of phase inversion temperature. However, different rheological profiles are observed depending on the surfactant concentration and water fraction. Viscosity maps of formulation-composition maps (specifically temperature–surfactant concentration and temperature–water fraction) pointed to the occurrence of both transitional and catastrophic inversion processes. A complete formulation–composition map with all different emulsion morphologies and isoviscosities contours for the 9% Brij30/IPM/water is presented. The use of a commercial cone–plate rheometer exhibits several advantages over the classical conductivity measurement; in particular, it does not imply any electrolyte addition in the aqueous phase and requires only a small volume of emulsion.Show less >
Language :
Anglais
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
ENSCL
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Collections :
Research team(s) :
Colloïdes catalyse oxydation (CÏSCO)
Submission date :
2019-09-25T14:04:46Z