Thermo‐physical properties of polypropylene ...
Document type :
Article dans une revue scientifique: Article original
DOI :
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Title :
Thermo‐physical properties of polypropylene fibers containing a microencapsulated flame retardant
Author(s) :
Salaun, Fabien [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Creach, G. [Auteur]
Université de Lille
Rault, François [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Almeras, X. [Auteur]
Ecole Nationale Supérieure de Chimie de Lille [ENSCL]

Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Creach, G. [Auteur]
Université de Lille
Rault, François [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Almeras, X. [Auteur]
Ecole Nationale Supérieure de Chimie de Lille [ENSCL]
Journal title :
Polymers for Advanced Technologies
Abbreviated title :
Polymers for Advanced Techs
Volume number :
24
Pages :
236-248
Publisher :
Wiley
Publication date :
2012-09-20
HAL domain(s) :
Sciences de l'ingénieur [physics]
English abstract : [en]
A microencapsulated flame retardant with a melamine‐formaldehyde shell was prepared by in situ polymerization, then incorporated into an iPP matrix with a coupling agent to manufacture multifilament yarns by melt spinning. ...
Show more >A microencapsulated flame retardant with a melamine‐formaldehyde shell was prepared by in situ polymerization, then incorporated into an iPP matrix with a coupling agent to manufacture multifilament yarns by melt spinning. The influence of the post‐treatment on the resulted microcapsules with an alcoholic solution was also studied. The spinnability of these formulations based on the interface characterization from contact angle measurements, tensile test and thermal characterizations was explored to determine the maximum draw ratio (DR) to apply. Finally, knitted fabrics were processed from multifilaments, and their flame‐retardant properties were evaluated by performing fire tests according to the FMVSS 302 and Din 4102 part B experiments. The different mechanical and thermal behaviors were discussed in terms of the influence of the DR and the post‐treatment applied on fibers during the spinning process and during the recovery of the microcapsules, respectively. The results showed that it was possible to obtain multifilament yarns with a DR of 4, but the best properties were obtained with a DR of 3 and for un‐treated microcapsules. Furthermore, the samples containing un‐treated microcapsules reach a B rating at the FMVSS test with a fast flame progression and a very low duration of burning. Copyright © 2012 John Wiley & Sons, Ltd.Show less >
Show more >A microencapsulated flame retardant with a melamine‐formaldehyde shell was prepared by in situ polymerization, then incorporated into an iPP matrix with a coupling agent to manufacture multifilament yarns by melt spinning. The influence of the post‐treatment on the resulted microcapsules with an alcoholic solution was also studied. The spinnability of these formulations based on the interface characterization from contact angle measurements, tensile test and thermal characterizations was explored to determine the maximum draw ratio (DR) to apply. Finally, knitted fabrics were processed from multifilaments, and their flame‐retardant properties were evaluated by performing fire tests according to the FMVSS 302 and Din 4102 part B experiments. The different mechanical and thermal behaviors were discussed in terms of the influence of the DR and the post‐treatment applied on fibers during the spinning process and during the recovery of the microcapsules, respectively. The results showed that it was possible to obtain multifilament yarns with a DR of 4, but the best properties were obtained with a DR of 3 and for un‐treated microcapsules. Furthermore, the samples containing un‐treated microcapsules reach a B rating at the FMVSS test with a fast flame progression and a very low duration of burning. Copyright © 2012 John Wiley & Sons, Ltd.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
ENSAIT
Junia HEI
ENSAIT
Junia HEI
Collections :
Research team(s) :
Multifunctional Textiles and Processes
Submission date :
2025-03-18T15:08:46Z
2025-03-19T10:13:59Z
2025-03-19T10:13:59Z
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