Hydroaminomethylation of oleochemicals: A ...
Document type :
Article dans une revue scientifique
DOI :
Permalink :
Title :
Hydroaminomethylation of oleochemicals: A comprehensive overview
Author(s) :
Vanbésien, Théodore [Auteur]
Le Nôtre, Jérôme [Auteur]
Monflier, Eric [Auteur]
UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Hapiot, Frederic [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
UCCS Équipe Catalyse Supramoléculaire
Le Nôtre, Jérôme [Auteur]
Monflier, Eric [Auteur]
UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Hapiot, Frederic [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
UCCS Équipe Catalyse Supramoléculaire
Journal title :
European Journal of Lipid Science and Technology
Volume number :
120
Pages :
1700190
Publisher :
Wiley
Publication date :
2018-01
English keyword(s) :
Catalysis
Fatty acid methyl esters
Hydroaminomethylation
Vegetable oils
Fatty acid methyl esters
Hydroaminomethylation
Vegetable oils
HAL domain(s) :
Chimie/Catalyse
English abstract : [en]
The present review explores the historical background of the rhodium‐catalyzed hydroaminomethylation (HAM) of vegetable oils and the recent developments in this field. The reaction conditions are especially discussed and ...
Show more >The present review explores the historical background of the rhodium‐catalyzed hydroaminomethylation (HAM) of vegetable oils and the recent developments in this field. The reaction conditions are especially discussed and commented upon. Various amines have been grafted onto alkyl chains of vegetable oils, thus giving rise to a wide range of bio‐based HAM‐products. A focus is on bifunctional HAM‐products as they have potential as monomers in polymer chemistry. The nature of the ligands stabilizing the rhodium catalytic species is also discussed. The catalytic results obtained with phosphanes and amines are analyzed and compared. The goal of this review is to convince the reader that HAM of vegetable oils is a simple and effective synthetic pathway to access valuable functionalized bio‐based compounds with industrial potential.Show less >
Show more >The present review explores the historical background of the rhodium‐catalyzed hydroaminomethylation (HAM) of vegetable oils and the recent developments in this field. The reaction conditions are especially discussed and commented upon. Various amines have been grafted onto alkyl chains of vegetable oils, thus giving rise to a wide range of bio‐based HAM‐products. A focus is on bifunctional HAM‐products as they have potential as monomers in polymer chemistry. The nature of the ligands stabilizing the rhodium catalytic species is also discussed. The catalytic results obtained with phosphanes and amines are analyzed and compared. The goal of this review is to convince the reader that HAM of vegetable oils is a simple and effective synthetic pathway to access valuable functionalized bio‐based compounds with industrial potential.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille
CNRS
Centrale Lille
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Catalyse et chimie supramoléculaire (CASU)
Submission date :
2019-09-25T14:06:05Z
2021-03-04T10:52:20Z
2021-03-04T10:52:20Z