Advances in Base-Free Oxidation of Bio-Based Compounds on Supported Gold Catalysts

Wojcieszak, Robert; Ferraz, Camila Palombo; Sha, Jin; Houda, Sarah; Rossi, Liane Marcia; PAUL, Sébastien

Type de document :

Article dans une revue scientifique: Article original

DOI :

10.3390/catal7110352

URL permanente :

http://hdl.handle.net/20.500.12210/12735

Titre :

Advances in Base-Free Oxidation of Bio-Based Compounds on Supported Gold Catalysts

Auteur(s) :

Wojcieszak, Robert [Auteur]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Ferraz, Camila Palombo [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Sha, Jin [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Houda, Sarah [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Rossi, Liane Marcia [Auteur]
Universidade de São Paulo = University of São Paulo [USP]
PAUL, Sébastien [Auteur]

Centrale Lille
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]

Titre de la revue :

Catalysts

Numéro :

Pagination :

352

Date de publication :

2017-11-15

ISSN :

2073-4344

Discipline(s) HAL :

Chimie/Catalyse

Résumé en anglais : [en]

The oxidation of bio-based molecules in general, and of carbohydrates and furanics in particular, is a highly attractive process. The catalytic conversion of renewable compounds is of high importance. Acids and other ...
Lire la suite >The oxidation of bio-based molecules in general, and of carbohydrates and furanics in particular, is a highly attractive process. The catalytic conversion of renewable compounds is of high importance. Acids and other chemical intermediates issued from oxidation processes have many applications related, especially, to food and detergents, as well as to pharmaceutics, cosmetics, and the chemical industry. Until now, the oxidation of sugars, furfural, or 5-hydroxymethylfurfural has been mainly conducted through biochemical processes or with strong inorganic oxidants. The use of these processes very often presents many disadvantages, especially regarding products separation and selectivity control. Generally, the oxidation is performed in batch conditions using an appropriate catalyst and a basic aqueous solution (pH 7–9), while bubbling oxygen or air through the slurry. However, there is a renewed interest in working in base-free conditions to avoid the production of salts. Actually, this gives direct access to different acids or diacids without laborious product purification steps. This review focuses on processes applying gold-based catalysts, and on the catalytic properties of these systems in the base-free oxidation of important compounds: C5–C6 sugars, furfural, and 5-hydroxymethylfurfural. A better understanding of the chemical and physical properties of the catalysts and of the operating conditions applied in the oxidation reactions is essential. For this reason, in this review we put emphasis on these most impacting factors.Lire moins >

Langue :

Anglais

Audience :

Internationale

Vulgarisation :

Non

Établissement(s) :

ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille

Collections :

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Équipe(s) de recherche :

Valorisation des alcanes et de la biomasse (VAALBIO)

Date de dépôt :

2019-09-25T14:06:26Z
2019-10-07T15:26:56Z
2023-01-11T10:03:52Z

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catalysts-07-00352-v2.pdf
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Ce document est diffusé sous licence Attribution 3.0 United States

Historique des modifications

Numéro de version	Lien	Date de modification
3	20.500.12210/12735*	2023-01-11T09:50:34Z
2	20.500.12210/12735.2	2019-10-07T15:25:21Z
1	20.500.12210/12735.1	2019-09-25T14:06:26Z

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