β-Keto-enol Tethered Pyridine and Thiophene: ...
Document type :
Article dans une revue scientifique: Article original
Permalink :
Title :
β-Keto-enol Tethered Pyridine and Thiophene: Synthesis, Crystal Structure Determination and Its Organic Immobilization on Silica for Efficient Solid-Liquid Extraction of Heavy Metals
Author(s) :
Radi, Smaail [Auteur]
Université Mohammed Premier [Oujda]
Tighadouini, Said [Auteur]
Université Mohammed Premier [Oujda]
Bacquet, maryse [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Degoutin, Stephanie [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Dacquin, Jean-Philippe [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Eddike, Driss [Auteur]
Université Mohammed Premier [Oujda]
Tillard, Monique [Auteur]
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
Mabkhot, Yahia [Auteur]
King Saud University [Riyadh] [KSU]
Université Mohammed Premier [Oujda]
Tighadouini, Said [Auteur]
Université Mohammed Premier [Oujda]
Bacquet, maryse [Auteur]

Unité Matériaux et Transformations - UMR 8207 [UMET]
Degoutin, Stephanie [Auteur]

Unité Matériaux et Transformations - UMR 8207 [UMET]
Dacquin, Jean-Philippe [Auteur]

Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Eddike, Driss [Auteur]
Université Mohammed Premier [Oujda]
Tillard, Monique [Auteur]
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
Mabkhot, Yahia [Auteur]
King Saud University [Riyadh] [KSU]
Journal title :
Molecules
Volume number :
21
Pages :
888
Publication date :
2016
English keyword(s) :
keto-enol
crystal structure
hybrid material
adsorption
heavy metals
crystal structure
hybrid material
adsorption
heavy metals
HAL domain(s) :
Chimie/Catalyse
English abstract : [en]
Molecules bearing β-keto-enol functionality are potential candidates for coordination chemistry. Reported herein is the first synthesis and use of a novel designed ligand based on β-keto-enol group embedded with pyridine ...
Show more >Molecules bearing β-keto-enol functionality are potential candidates for coordination chemistry. Reported herein is the first synthesis and use of a novel designed ligand based on β-keto-enol group embedded with pyridine and thiophene moieties. The product was prepared in a one-step procedure by mixed Claisen condensation and was characterized by EA, m/z, FT-IR, (1H, 13C) NMR and single-crystal X-ray diffraction analysis. The new structure was grafted onto silica particles to afford a chelating matrix which was well-characterized by EA, FT-IR, solid-state 13C-NMR, BET, BJH, SEM and TGA. The newly prepared organic-inorganic material was used as an adsorbent for efficient solid-phase extraction (SPE) of Cu(II), Zn(II), Cd(II) and Pb(II) from aqueous solutions and showed a capture capacity of 104.12 mg·g−1, 98.90 mg·g−1, 72.02 mg·g−1, and 65.54 mg·g−1, respectively. The adsorption capacity was investigated, in a batch method, using time of contact, pH, initial concentration, kinetics (Langmuir and Freundlich models), and thermodynamic parameters (ΔG°, ΔH° and ΔS°) of the system effects.Show less >
Show more >Molecules bearing β-keto-enol functionality are potential candidates for coordination chemistry. Reported herein is the first synthesis and use of a novel designed ligand based on β-keto-enol group embedded with pyridine and thiophene moieties. The product was prepared in a one-step procedure by mixed Claisen condensation and was characterized by EA, m/z, FT-IR, (1H, 13C) NMR and single-crystal X-ray diffraction analysis. The new structure was grafted onto silica particles to afford a chelating matrix which was well-characterized by EA, FT-IR, solid-state 13C-NMR, BET, BJH, SEM and TGA. The newly prepared organic-inorganic material was used as an adsorbent for efficient solid-phase extraction (SPE) of Cu(II), Zn(II), Cd(II) and Pb(II) from aqueous solutions and showed a capture capacity of 104.12 mg·g−1, 98.90 mg·g−1, 72.02 mg·g−1, and 65.54 mg·g−1, respectively. The adsorption capacity was investigated, in a batch method, using time of contact, pH, initial concentration, kinetics (Langmuir and Freundlich models), and thermodynamic parameters (ΔG°, ΔH° and ΔS°) of the system effects.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
ENSCL
CNRS
INRA
Centrale Lille
Univ. Artois
Université de Lille
CNRS
INRA
Centrale Lille
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Matériaux pour la catalyse (MATCAT)
Submission date :
2019-09-25T14:38:12Z
2020-05-05T15:14:05Z
2020-05-05T15:14:05Z
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