Title :

Synthesis and multifaceted use of phosphorylated graphene oxide: growth of titanium dioxide clusters, interplay with gold nanoparticles and exfoliated sheets in bioplastics

Author(s) :

Anouar, Aicha [Auteur]

Katir, Nadia [Auteur]
Mamede, Anne-Sophie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Aboulaich, Abdelhay [Auteur]
Institut de Chimie de Clermont-Ferrand [ICCF]
Draoui, Khalid [Auteur]

Royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
El Kadib, Abdelkrim [Auteur]

Journal title :

Materials Chemistry Frontiers

Volume number :

3

Pages :

242-250

Publication date :

2019-02-01

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

Five different functional phosphorus motifs were trivially installed within graphene oxide (GO) sheets to provide water-dispersible and thermally-stable phosphorus graphene oxide materials (PGO). The presence of exogenous ...
Show more >Five different functional phosphorus motifs were trivially installed within graphene oxide (GO) sheets to provide water-dispersible and thermally-stable phosphorus graphene oxide materials (PGO). The presence of exogenous phosphorus heteroatoms on the surface of the tiny carbon sheets was harnessed for the anchoring and growth of metal oxide clusters, exemplified herein by titanium dioxide, and for the chelation and stabilization of small gold nanoparticles. Unexpectedly, both GO and PGO promoted crystallization in a low-temperature liquid-phase medium without thermal annealing treatment. However, the fingerprint of the surface chemistry is illustrated through the formation of different species; while discrete anatase nanoparticles were selectively formed on the surface of GO sheets, a biphasic mixture of anatase and rutile was grown on PGO. The latter provides a more stable material owing to the robustness of the interfacial P–O–Ti bridges. Strong coordination to gold nanoparticles was also observed for PGO due to the presence of P[double bond, length as m-dash]O(OH)2 fragments, compared to the weakly coordinating oxygenated functions in GO. Lastly, the possible delamination of PGO sheets associated with their improved thermal stability renders them promising nanosized fillers for carbohydrate-based bioplastics.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

ENSCL
CNRS
Centrale Lille
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Matériaux pour la catalyse (MATCAT)

Submission date :

2019-09-25T15:07:10Z
2020-10-23T13:21:55Z