Title :

The flammability and mechanical properties of poly (lactic acid) composites containing Ni-MOF nanosheets with polyhydroxy groups

Author(s) :

Wang, Xingguo [Auteur]
Wang, Shuheng [Auteur]
Wang, Wenjia [Auteur]
Li, Hongfei [Auteur]
Liu, Xiaodong [Auteur]
Gu, Xiaoyu [Auteur]
Bourbigot, Serge [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Wang, Zhongwei [Auteur]
Sun, Jun [Auteur]
Zhang, Sheng [Auteur]

Journal title :

Composites Part B: Engineering

Abbreviated title :

Composites Part B: Engineering

Pages :

107568

Publisher :

Elsevier BV

Publication date :

2020-02

ISSN :

1359-8368

HAL domain(s) :

Chimie/Matériaux
Chimie/Polymères

English abstract : [en]

This work reports our recent effort on the preparation of α-Phenyl-N-(2-propyl-2-hydroxymethyl-1, 3-dihydroxy)-imine-Nickel (II) (Ni-MOF) containing polyhydroxy groups and its application in improving the fire performance ...
Show more >This work reports our recent effort on the preparation of α-Phenyl-N-(2-propyl-2-hydroxymethyl-1, 3-dihydroxy)-imine-Nickel (II) (Ni-MOF) containing polyhydroxy groups and its application in improving the fire performance of PLA composites in combination with ammonium polyphosphate (APP). The flame retardant evaluation revealed that the presence of 1.7% Ni-MOF and 3.3% APP in PLA increased the LOI value to 31.0%, upgraded the UL-94 level to V-0, decreased the peak heat release rate (pHRR), total heat release (THR) and total smoking production (TSP) by 27%, 19% and 50%, respectively, and substantially delayed the time to ignition (TTI) from 67 to 97 s. It was proposed that the flame retardants take effect in both vapor and condensed phases, and Ni-MOF nanosheets can synergistically improve the flame resistance of PLA with APP. The incorporation of Ni-MOF effectively inhibited the deterioration of mechanical properties for PLA composites caused by the presence of APP.Show less >

Language :

Anglais

Audience :

Non spécifiée

Administrative institution(s) :

Université de Lille
CNRS
INRA
ENSCL

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Ingénierie des Systèmes Polymères

Submission date :

2019-12-20T17:21:16Z
2020-01-06T09:11:56Z