Title :

Comparative studies of thermal and mechanical properties of macrocyclic versus linear polylactide

Author(s) :

Louisy, Elodie [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Fontaine, Gaelle [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Gaucher, Valerie [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Bonnet, Fanny [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Stoclet, Grégory [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]

Journal title :

Polymer Bulletin

Abbreviated title :

Polym. Bull.

Volume number :

78

Pages :

3763

Publisher :

Springer Science and Business Media LLC

Publication date :

2021-06-08

HAL domain(s) :

Chimie/Matériaux
Chimie/Polymères

English abstract : [en]

This paper reports the study of the influence of the macrocyclic or linear topology of polylactide (PLA) on its resulting thermal and mechanical properties, when displaying identical molar masses. Even if both macrocyclic ...
Show more >This paper reports the study of the influence of the macrocyclic or linear topology of polylactide (PLA) on its resulting thermal and mechanical properties, when displaying identical molar masses. Even if both macrocyclic and linear PLAs crystallize in the same α phase, the results of the calorimetric study and of the tensile tests show some differences which are directly related to the topology of the polymer. The glass transition temperature of macrocyclic PLA was found to be slightly higher than that of the linear one (56 vs 53 °C) while its melting temperature is lower (165 vs 171 °C). Moreover, the crystallization rate of the macrocyclic PLA is slower than that of the linear PLA. Regarding the tensile tests, it has been observed that the macrocyclic PLA displays an earlier strain-hardening than the linear one when stretched in the rubbery state. These differences were attributed to the fact that the macrocyclic topology involves a more constrained entangled network than its linear analogous and/or that the disentanglement kinetics is faster in linear PLA than in macrocylic PLA.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

Université de Lille
CNRS
INRA
ENSCL

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Ingénierie des Systèmes Polymères

Submission date :

2020-07-08T12:25:00Z
2020-07-18T13:13:57Z
2020-09-01T13:41:30Z
2021-07-12T12:15:12Z