Dimers of polycyclic aromatic hydrocarbons: ...
Type de document :
Compte-rendu et recension critique d'ouvrage
DOI :
Titre :
Dimers of polycyclic aromatic hydrocarbons: the missing pieces in the soot formation process
Auteur(s) :
Mercier, Xavier [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Carrivain, Olivier [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Irimiea, Cornélia [Auteur]
DMPE, ONERA, Université Paris Saclay (COmUE) [Palaiseau]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Faccinetto, Alessandro [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Therssen, Eric [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Carrivain, Olivier [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Irimiea, Cornélia [Auteur]
DMPE, ONERA, Université Paris Saclay (COmUE) [Palaiseau]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Faccinetto, Alessandro [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Therssen, Eric [Auteur]
Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522 [PC2A]
Titre de la revue :
Physical Chemistry Chemical Physics
Pagination :
8282-8294
Éditeur :
Royal Society of Chemistry
Date de publication :
2019
ISSN :
1463-9076
Mot(s)-clé(s) en anglais :
laser induced fluorescence (LIF)
dimers of PAHs
polycyclic aromatic hydrocarbons (PAHs)
soot nucleation
dimers of PAHs
polycyclic aromatic hydrocarbons (PAHs)
soot nucleation
Discipline(s) HAL :
Chimie/Chimie théorique et/ou physique
Chimie/Chimie organique
Chimie/Chimie organique
Résumé en anglais : [en]
The soot nucleation process, defined as the transition from molecular precursors to condensed matter, is the less understood step in the whole soot formation process. The possibility that polycyclic aromatic hydrocarbon ...
Lire la suite >The soot nucleation process, defined as the transition from molecular precursors to condensed matter, is the less understood step in the whole soot formation process. The possibility that polycyclic aromatic hydrocarbon (PAH) dimers, especially those containing moderate-sized PAHs, can play a major role in soot nucleation is a very controversial issue. Although PAH dimers have often been considered as potential soot precursors, their formation is not thermodynamically favored at a typical flame temperature, their binding energies being considered too weak to allow them to survive in this environment. Hereby, we report experimental evidence supporting the existence of PAH dimers in the proximity of the soot nucleation region of a methane laminar diffusion flame that gives strong evidence for the nucleation process to be kinetically rather than thermodynamically controlled.Lire moins >
Lire la suite >The soot nucleation process, defined as the transition from molecular precursors to condensed matter, is the less understood step in the whole soot formation process. The possibility that polycyclic aromatic hydrocarbon (PAH) dimers, especially those containing moderate-sized PAHs, can play a major role in soot nucleation is a very controversial issue. Although PAH dimers have often been considered as potential soot precursors, their formation is not thermodynamically favored at a typical flame temperature, their binding energies being considered too weak to allow them to survive in this environment. Hereby, we report experimental evidence supporting the existence of PAH dimers in the proximity of the soot nucleation region of a methane laminar diffusion flame that gives strong evidence for the nucleation process to be kinetically rather than thermodynamically controlled.Lire moins >
Langue :
Anglais
Vulgarisation :
Non
Projet ANR :
Source :
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