Title :

Electronic state spectroscopy of 1,4-pentadiene as studied by VUV photoabsorption spectroscopy and ab initio calculations.

Author(s) :

Sério, S. [Auteur]
Nunes, Y. [Auteur]
Hoffman, S.V. [Auteur]
Centre for Storage Ring Facilities [Aarhus] [ISA]
Mason, N.J. [Auteur]
Duflot, Denis [Auteur]
Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 [PhLAM]
Limão-Vieira, Paulo [Auteur]

Journal title :

Journal of Physical Chemistry A

Pages :

8176-84

Publisher :

American Chemical Society

Publication date :

2012-08-09

ISSN :

1089-5639

HAL domain(s) :

Chimie/Chimie théorique et/ou physique

English abstract : [en]

We present high resolution VUV photoabsorption spectra of 1,4-pentadiene, C(5)H(8), over the wavelength range 115-247 nm (10.8-5.0 eV). These spectra reveal several new features not previously reported in the literature. ...
Show more >We present high resolution VUV photoabsorption spectra of 1,4-pentadiene, C(5)H(8), over the wavelength range 115-247 nm (10.8-5.0 eV). These spectra reveal several new features not previously reported in the literature. These measurements are complemented by the first ab initio calculations for the three most abundant conformational isomers of 1,4-pentadiene, C(5)H(8), which we then use in the assignment of valence and Rydberg transitions. Calculations of the two lowest energy ionic states of 1,4-pentadiene are also presented and compared with the experimental data available in the literature. The measured absolute photoabsorption cross sections have been used to calculate the photolysis lifetime of 1,4-pentadiene in the upper stratosphere (20-50 km).Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Collections :

• Laboratoire de Physique des Lasers, Atomes et Molécules (PhLAM) - UMR 8523

Source :

Harvested from HAL