Title :

Effect of Host–Guest Complexation on the Thermoresponsive Behavior of Poly(oligo ethylene glycol acrylate)s Functionalized with Dialkoxynapththalene Guest Side Chains

Author(s) :

Ryskulova, Kanykei [Auteur]
Universiteit Gent = Ghent University [UGENT]
Hou, Zhanyao [Auteur]
Universiteit Gent = Ghent University [UGENT]
Woisel, Patrice [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Hoogenboom, Richard [Auteur]
Universiteit Gent = Ghent University [UGENT]

Journal title :

Macromolecular Rapid Communications

Abbreviated title :

Macromol. Rapid Commun.

Pages :

2100068

Publisher :

Wiley

Publication date :

2021-03-22

English keyword(s) :

host–guest complexation
LCST
responsive polymers
supramolecular chemistry

HAL domain(s) :

Chimie/Matériaux
Chimie/Polymères

English abstract : [en]

The combination of thermoresponsive polymers with supramolecular host–guest interactions enables accurate tuning of the phase transition temperature, while also providing additional response mechanisms based on host–guest ...
Show more >The combination of thermoresponsive polymers with supramolecular host–guest interactions enables accurate tuning of the phase transition temperature, while also providing additional response mechanisms based on host–guest complexation. Most studies focused on a single thermoresponsive polymer to demonstrate the effect of host–guest complexation on the responsive behavior. In this work, the effect of the polymer structure on the host–guest complexation and thermoresponsive behavior is reported. Therefore, different poly(oligoethylene glycol acrylate)s, namely, poly(2‐hydroxyethylacrylate) (PHEA), poly(methoxy diethylene glycol acrylate), poly(methoxy triethylene glycol acrylate), and poly(methoxy tetraethylene glycol acrylate), are synthesized functionalized with 1,5‐dialkoxynaphthalene guest molecules in the side chain. Their complexation with the cyclobis(paraquat‐p‐phenylene) tetrachloride host is studied to understand the effect of polymer structure on the supramolecular association and the polymer phase transition, revealing that the oligoethylene glycol side chains lead to weaker host–guest complexation and also have a smaller increase in the cloud point temperature compared to PHEA.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

Université de Lille
CNRS
INRA
ENSCL

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Ingénierie des Systèmes Polymères

Submission date :

2021-03-31T13:36:00Z
2021-04-15T10:26:57Z