Title :

Behaviour and origin of hydrogen defects in natural orthopyroxene during high-temperature processes

Author(s) :

Yang, Yan [Auteur]
Zhejiang University [Hangzhou, China]
Ingrin, Jannick [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Unité Matériaux et Transformations - UMR 8207 [UMET]
Liu, Wendi [Auteur]
Zhejiang University [Hangzhou, China]
Huang, Weihua [Auteur]
Zhejiang University [Hangzhou, China]
Gu, Xiaoyan [Auteur]
Zhejiang University [Hangzhou, China]
Xia, Qunke [Auteur]
Zhejiang University [Hangzhou, China]

Journal title :

The American Mineralogist

Abbreviated title :

msam

Volume number :

106

Publisher :

Mineralogical Society of America

Publication date :

2021-10-01

ISSN :

1945-3027

English keyword(s) :

Hydrogen defect
Diffusivity
Re-distribution
Orthopyroxene
High temperature
FTI

HAL domain(s) :

Planète et Univers [physics]/Sciences de la Terre
Planète et Univers [physics]/Astrophysique [astro-ph]
Physique [physics]/Astrophysique [astro-ph]
Physique [physics]/Physique [physics]/Géophysique [physics.geo-ph]
Physique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]
Chimie/Matériaux

English abstract : [en]

Spectral features of hydrogen defects in natural mantle minerals derive from physico-chemical conditions of the lithosphere. Although hydrogen defects in synthetic orthopyroxene have been well investigated, ...
Show more >Spectral features of hydrogen defects in natural mantle minerals derive from physico-chemical conditions of the lithosphere. Although hydrogen defects in synthetic orthopyroxene have been well investigated, their complex spectral features in natural orthopyroxenes are still difficult to decipher. To clarify this issue, it is indispensable to reveal what happens to hydrogen defects during high temperature processes, thereby fingerprinting the origins of hydrogen defects observed in natural orth opyroxene. Here, we carry out Fourier transform infrared spectroscopic studies on hydrogen defects of three natural orthopyroxenes at elevated temperatures to 1000 oC. Hydrogen defects display reversible disordering at temperatures above 700 oC, which is different to those at ambien t c onditions. Moreover, hydrogen diffusivities are significantly different between the orthopyroxene samples from different tectonic settings despite their similar iron contents. Even for the same crystal, different hydrogen defects display different diffusion behaviors . Hydrogen defects corresponding to the 3420 cm-1 band have the fastest diffusivity relative to the other hydrogen defects. Most importantly, hydrogen defects can re-distribute in the crystal, with new hydrogen defects produced at the cost of the initial h ydrogen defects rather than involving reaction with an external hydrogen source. Combining these findings with previously reported hydrogen defects in natural olivine and clinopyroxene at high temperatures, we propose that (1) to correctly relate hydrogen defects features to geological processes, it is imperative to understand their behavior and origin, (2) hydrogen disordering should be taken into account when predicting and extrapolating data on physical properties of the mantle from room -temperature measurements.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Administrative institution(s) :

ENSCL
INRA
CNRS
Université de Lille

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Matériaux Terrestres et Planétaires

Submission date :

2021-08-11T10:44:17Z
2021-08-30T08:15:38Z
2021-08-30T08:17:13Z