Identifying isomers of peroxy radicals in ...
Document type :
Article dans une revue scientifique
DOI :
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Title :
Identifying isomers of peroxy radicals in the gas phase: 1-C3H7O2vs. 2-C3H7O2
Author(s) :
Tang, Xiaofeng [Auteur]
University of Science and Technology of China [Hefei] [USTC]
Lin, Xiaoxiao [Auteur]
University of Science and Technology of China [Hefei] [USTC]
Garcia, Gustavo A. [Auteur]
Synchrotron SOLEIL [SSOLEIL]
Loison, Jean-Christophe [Auteur]
Institut des Sciences Moléculaires [ISM]
Gouid, Zied [Auteur]
Laboratoire Instrumentation, Simulation et Informatique Scientifique [COSYS-LISIS]
Abdallah, Hassan H. [Auteur]
Fittschen, Christa [Auteur]
Physicochimie des Processus de Combustion et de l'Atmosphère (PC2A) - UMR 8522
Hochlaf, Majdi [Auteur]
Laboratoire Instrumentation, Simulation et Informatique Scientifique [COSYS-LISIS]
Gu, Xuejun [Auteur]
University of Science and Technology of China [Hefei] [USTC]
Zhang, Weijun [Auteur]
University of Science and Technology of China [Hefei] [USTC]
Nahon, Laurent [Auteur]
Synchrotron SOLEIL [SSOLEIL]
University of Science and Technology of China [Hefei] [USTC]
Lin, Xiaoxiao [Auteur]
University of Science and Technology of China [Hefei] [USTC]
Garcia, Gustavo A. [Auteur]
Synchrotron SOLEIL [SSOLEIL]
Loison, Jean-Christophe [Auteur]
Institut des Sciences Moléculaires [ISM]
Gouid, Zied [Auteur]
Laboratoire Instrumentation, Simulation et Informatique Scientifique [COSYS-LISIS]
Abdallah, Hassan H. [Auteur]
Fittschen, Christa [Auteur]

Physicochimie des Processus de Combustion et de l'Atmosphère (PC2A) - UMR 8522
Hochlaf, Majdi [Auteur]
Laboratoire Instrumentation, Simulation et Informatique Scientifique [COSYS-LISIS]
Gu, Xuejun [Auteur]
University of Science and Technology of China [Hefei] [USTC]
Zhang, Weijun [Auteur]
University of Science and Technology of China [Hefei] [USTC]
Nahon, Laurent [Auteur]
Synchrotron SOLEIL [SSOLEIL]
Journal title :
Chemical Communications
Abbreviated title :
Chem. Commun.
Volume number :
56
Pages :
15525-15528
Publisher :
Royal Society of Chemistry (RSC)
Publication date :
2020-11-19
ISSN :
1359-7345
HAL domain(s) :
Physique [physics]
Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
Chimie/Chimie théorique et/ou physique
Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]
Chimie/Chimie théorique et/ou physique
English abstract : [en]
The two isomers of the propylperoxy radical 1-C3H7O2 and 2-C3H7O2, together with their individual rotamers, are identified and assigned by threshold photoelectron spectroscopy with the aid of high-level theoretical ...
Show more >The two isomers of the propylperoxy radical 1-C3H7O2 and 2-C3H7O2, together with their individual rotamers, are identified and assigned by threshold photoelectron spectroscopy with the aid of high-level theoretical computations, from which their accurate adiabatic ionization energies are derived. This study paves the way to probing elusive peroxy radicals and their isomers in advanced mass spectrometry analysis of combustion and atmospheric reactions.Show less >
Show more >The two isomers of the propylperoxy radical 1-C3H7O2 and 2-C3H7O2, together with their individual rotamers, are identified and assigned by threshold photoelectron spectroscopy with the aid of high-level theoretical computations, from which their accurate adiabatic ionization energies are derived. This study paves the way to probing elusive peroxy radicals and their isomers in advanced mass spectrometry analysis of combustion and atmospheric reactions.Show less >
Language :
Anglais
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
CNRS
CNRS
Research team(s) :
PhysicoChimie de l'Atmosphère (PCA)
Submission date :
2021-08-24T14:56:57Z
2021-08-30T09:16:21Z
2021-08-30T09:16:21Z
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