Title :

Deformation of NaCoF3 perovskite and post-perovskite up to 30 GPa and 1013 K: implications for plastic deformation and transformation mechanism

Author(s) :

Gay, Jeffrey-Phillip [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Miyagi, Lowell [Auteur]
University of Utah
Couper, Samantha [Auteur]
University of Utah
Langrand, Christopher [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Dobson, David P. [Auteur]
University College of London [London] [UCL]
Liermann, Hanns-Peter [Auteur]
Deutsches Elektronen-Synchrotron [Hamburg] [DESY]
Merkel, Sébastien [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207

Journal title :

European Journal of Mineralogy

Abbreviated title :

Eur. J. Mineral.

Volume number :

33

Pages :

591-603

Publisher :

Copernicus Publications

Publication date :

2021-09-30

ISSN :

0935-1221

HAL domain(s) :

Chimie/Matériaux
Physique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]
Physique [physics]/Physique [physics]/Géophysique [physics.geo-ph]
Physique [physics]/Astrophysique [astro-ph]
Planète et Univers [physics]/Astrophysique [astro-ph]
Planète et Univers [physics]/Sciences de la Terre

English abstract : [en]

Texture, plastic deformation, and phase transformation mechanisms in perovskite and post-perovskite are of general interest for our understanding of the Earth's mantle. Here, the perovskite analogue NaCoF3 is deformed ...
Show more >Texture, plastic deformation, and phase transformation mechanisms in perovskite and post-perovskite are of general interest for our understanding of the Earth's mantle. Here, the perovskite analogue NaCoF3 is deformed in a resistive-heated diamond anvil cell (DAC) up to 30 GPa and 1013 K. The in situ state of the sample, including crystal structure, stress, and texture, is monitored using X-ray diffraction. A phase transformation from a perovskite to a post-perovskite structure is observed between 20.1 and 26.1 GPa. Normalized stress drops by a factor of 3 during transformation as a result of transient weakening during the transformation. The perovskite phase initially develops a texture with a maximum at 100 and a strong 010 minimum in the inverse pole figure of the compression direction. Additionally, a secondary weaker 001 maximum is observed later during compression. Texture simulations indicate that the initial deformation of perovskite requires slip along (100) planes with significant contributions of {110} twins. Following the phase transition to post-perovskite, we observe a 010 maximum, which later evolves with compression. The transformation follows orientation relationships previously suggested where the c axis is preserved between phases and hh0 vectors in reciprocal space of post-perovskite are parallel to [010] in perovskite, which indicates a martensitic-like transition mechanism. A comparison between past experiments on bridgmanite and current results indicates that NaCoF3 is a good analogue to understand the development of microstructures within the Earth's mantle.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Related reference(s) :

http://hdl.handle.net/20.500.12210/55822

European Project :

Convenient Access to Light Sources Open to Innovation, Science and to the World

ANR Project :

Transformations de phase, microstructures, et leur signatures sismiques dans le manteau terrestre

Administrative institution(s) :

Université de Lille
CNRS
INRA
ENSCL

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Matériaux Terrestres et Planétaires

Submission date :

2021-10-04T16:29:58Z
2021-10-06T08:20:27Z