Synthesis and characterization of palladium ...
Document type :
Compte-rendu et recension critique d'ouvrage
Title :
Synthesis and characterization of palladium nanoparticles immobilized on graphene oxide functionalized with triethylenetetramine or 2,6-diaminopyridine and application for the Suzuki cross-coupling reaction
Author(s) :
Mirza-Aghayan, Maryam [Auteur]
Mohammadi, Marzieh [Auteur]
Boukherroub, Rabah [Auteur]
NanoBioInterfaces - IEMN [NBI - IEMN]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Mohammadi, Marzieh [Auteur]
Boukherroub, Rabah [Auteur]

NanoBioInterfaces - IEMN [NBI - IEMN]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Journal title :
Journal of Organometallic Chemistry
Pages :
122160
Publisher :
Elsevier
Publication date :
2022-01
ISSN :
0022-328X
English keyword(s) :
Graphene oxide derivatives
Palladium nanoparticles
Triethylenetetramine2
6-Diaminopyridine
Suzuki cross-coupling reaction
Palladium nanoparticles
Triethylenetetramine2
6-Diaminopyridine
Suzuki cross-coupling reaction
HAL domain(s) :
Sciences de l'ingénieur [physics]
Chimie
Chimie
English abstract : [en]
Graphene oxide (GO) was functionalized with two organic ligands, triethylenetetramine (TETA) or 2,6-diaminopyridine (DAP), followed by palladium nanoparticles (Pd NPs) for the synthesis of Pd NPs/GO-TETA and Pd NPs/GO-DAP ...
Show more >Graphene oxide (GO) was functionalized with two organic ligands, triethylenetetramine (TETA) or 2,6-diaminopyridine (DAP), followed by palladium nanoparticles (Pd NPs) for the synthesis of Pd NPs/GO-TETA and Pd NPs/GO-DAP nanocomposites, respectively. The two heterogeneous nanocomposites were fully characterized and their efficiency was investigated for C-C bond formation for the synthesis of biaryl compounds via the Suzuki cross-coupling reaction of aryl halides with arylboronic acid derivatives. The obtained results indicated that the Pd NPs/GO-TETA nanocomposite was more effective in the Suzuki coupling reaction as compared to Pd NPs/GO-DAP. Thus, the Suzuki cross-coupling reaction of different aryl halides with arylboronic acid derivatives using Pd NPs/GO-TETA nanocomposite catalyst in the presence of Na2CO3 as base in DMF/H2O (1 /1) as solvent at 90 degrees C was carried out to afford the desired biaryl compounds in high to excellent yields (81-100%) and short reaction times (10-90 min). Additionally, Pd NPs/GO-TETA nanocomposite can be recovered and reused for 8 consecutive runs without any apparent loss of its catalytic activity, proving its high stability and potential use in organic transformations. (C) 2021 Elsevier B.V. All rights reserved.Show less >
Show more >Graphene oxide (GO) was functionalized with two organic ligands, triethylenetetramine (TETA) or 2,6-diaminopyridine (DAP), followed by palladium nanoparticles (Pd NPs) for the synthesis of Pd NPs/GO-TETA and Pd NPs/GO-DAP nanocomposites, respectively. The two heterogeneous nanocomposites were fully characterized and their efficiency was investigated for C-C bond formation for the synthesis of biaryl compounds via the Suzuki cross-coupling reaction of aryl halides with arylboronic acid derivatives. The obtained results indicated that the Pd NPs/GO-TETA nanocomposite was more effective in the Suzuki coupling reaction as compared to Pd NPs/GO-DAP. Thus, the Suzuki cross-coupling reaction of different aryl halides with arylboronic acid derivatives using Pd NPs/GO-TETA nanocomposite catalyst in the presence of Na2CO3 as base in DMF/H2O (1 /1) as solvent at 90 degrees C was carried out to afford the desired biaryl compounds in high to excellent yields (81-100%) and short reaction times (10-90 min). Additionally, Pd NPs/GO-TETA nanocomposite can be recovered and reused for 8 consecutive runs without any apparent loss of its catalytic activity, proving its high stability and potential use in organic transformations. (C) 2021 Elsevier B.V. All rights reserved.Show less >
Language :
Anglais
Popular science :
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