Enantioselective nickel catalyzed butadiene ...
Document type :
Article dans une revue scientifique: Article original
Permalink :
Title :
Enantioselective nickel catalyzed butadiene hydroalkoxylation with ethanol: from experimental results to kinetics parameters
Author(s) :
Mifleur, Alexis [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Suisse, Isabelle [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Mortreux, Andre [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Sauthier, Mathieu [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Suisse, Isabelle [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Mortreux, Andre [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Sauthier, Mathieu [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Journal title :
Catalysis Letters
Abbreviated title :
Catal. Lett.
Volume number :
151
Pages :
27-35
Publication date :
2020-06-27
ISSN :
1011-372X
Keyword(s) :
Homogeneous catalysis
Chiral diphosphines
Butadiene
Kinetics
Nickel
Chiral diphosphines
Butadiene
Kinetics
Nickel
HAL domain(s) :
Chimie/Catalyse
English abstract : [en]
The enantioselective hydroalkoxylation of butadiene with ethanol has been performed in the presence of nickel-based catalysts and chiral diphosphine ligands. Ee’s up to 77% could be obtained from the use of atropoisomeric ...
Show more >The enantioselective hydroalkoxylation of butadiene with ethanol has been performed in the presence of nickel-based catalysts and chiral diphosphine ligands. Ee’s up to 77% could be obtained from the use of atropoisomeric chiral ligands such as Segphos. The kinetics parameters of the reaction were determined using a qualitative kinetic model to better explain the l/b isomerization and racemization processes observed for long reaction times.Show less >
Show more >The enantioselective hydroalkoxylation of butadiene with ethanol has been performed in the presence of nickel-based catalysts and chiral diphosphine ligands. Ee’s up to 77% could be obtained from the use of atropoisomeric chiral ligands such as Segphos. The kinetics parameters of the reaction were determined using a qualitative kinetic model to better explain the l/b isomerization and racemization processes observed for long reaction times.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Catalyse et synthèse éco-compatible (CASECO)
Submission date :
2022-03-02T07:14:45Z
2023-11-06T17:11:43Z
2023-11-06T17:11:43Z
Files
- mifleur asym version revised version_verif titres IS 11-05.pdf
- Version finale acceptée pour publication (postprint)
- Open access
- Access the document