Rhodium-Catalyzed Aqueous Biphasic Olefin ...
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Article dans une revue scientifique: Article original
DOI :
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Title :
Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins
Author(s) :
Cocq, Aurélien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Bricout, Herve [Auteur]
UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Djedaïni-Pilard, Florence [Auteur]
Laboratoire de Glycochimie, des Antimicrobiens et des Agro-ressources - UMR CNRS 7378 [LG2A ]
Université de Picardie Jules Verne [UPJV]
Tilloy, Sebastien [Auteur]
UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Monflier, Eric [Auteur]
UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Bricout, Herve [Auteur]

UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Djedaïni-Pilard, Florence [Auteur]
Laboratoire de Glycochimie, des Antimicrobiens et des Agro-ressources - UMR CNRS 7378 [LG2A ]
Université de Picardie Jules Verne [UPJV]
Tilloy, Sebastien [Auteur]

UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Monflier, Eric [Auteur]

UCCS Équipe Catalyse Supramoléculaire
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Journal title :
Catalysts
Volume number :
10
Pages :
56
Publisher :
MDPI
Publication date :
2020-01-01
ISSN :
2073-4344
HAL domain(s) :
Chimie
English abstract : [en]
Hydroformylation is an industrial process that allows for the production of aldehydes from alkenes using transition metals. The reaction can be carried out in water, and the catalyst may be recycled at the end of the ...
Show more >Hydroformylation is an industrial process that allows for the production of aldehydes from alkenes using transition metals. The reaction can be carried out in water, and the catalyst may be recycled at the end of the reaction. The industrial application of rhodium-catalyzed aqueous hydroformylation has been demonstrated for smaller olefins (propene and butene). Unfortunately, larger olefins are weakly soluble in water, which results in very low catalytic activity. In an attempt to counteract this, we investigated the use of amphiphilic oleic succinyl-cyclodextrins (OS-CDs) synthesized from oleic acid derivatives and maleic anhydride. OS-CDs were found to increase the catalytic activity of rhodium during the hydroformylation of water-insoluble olefins, such as 1-decene and 1-hexadecene, by promoting mass transfer. Recyclability of the catalytic system was also evaluated in the presence of these cyclodextrins.Show less >
Show more >Hydroformylation is an industrial process that allows for the production of aldehydes from alkenes using transition metals. The reaction can be carried out in water, and the catalyst may be recycled at the end of the reaction. The industrial application of rhodium-catalyzed aqueous hydroformylation has been demonstrated for smaller olefins (propene and butene). Unfortunately, larger olefins are weakly soluble in water, which results in very low catalytic activity. In an attempt to counteract this, we investigated the use of amphiphilic oleic succinyl-cyclodextrins (OS-CDs) synthesized from oleic acid derivatives and maleic anhydride. OS-CDs were found to increase the catalytic activity of rhodium during the hydroformylation of water-insoluble olefins, such as 1-decene and 1-hexadecene, by promoting mass transfer. Recyclability of the catalytic system was also evaluated in the presence of these cyclodextrins.Show less >
Language :
Anglais
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Catalyse et chimie supramoléculaire (CASU)
Submission date :
2022-03-08T13:48:12Z
2023-02-01T08:03:02Z
2023-02-01T08:03:02Z
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