Amyl Xyloside, a Selective Sugar-Based ...
Document type :
Article dans une revue scientifique: Article original
Permalink :
Title :
Amyl Xyloside, a Selective Sugar-Based Hydrotrope for the Aqueous Extraction of Carnosic Acid from Rosemary
Author(s) :
Mazaud, Agathe [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Lebeuf, Raphael [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Pierlot, Christel [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Laguerre, Mickaël [Auteur]
Naturex SA [Avignon]
Nardello-Rataj, Véronique [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Lebeuf, Raphael [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Pierlot, Christel [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Laguerre, Mickaël [Auteur]
Naturex SA [Avignon]
Nardello-Rataj, Véronique [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Journal title :
ACS Sustainable Chemistry & Engineering
Abbreviated title :
ACS Sustainable Chem. Eng.
Volume number :
9
Pages :
4801-4811
Publication date :
2021-04-05
ISSN :
2168-0485, 2168-0485
HAL domain(s) :
Chimie/Chimie organique
English abstract : [en]
Rosemary (Rosmarinus officinalis L.) is a Mediterranean herb known for its high antioxidant power that has been widely attributed to carnosic acid (CA). Passive extractions of CA have been performed in water by using five ...
Show more >Rosemary (Rosmarinus officinalis L.) is a Mediterranean herb known for its high antioxidant power that has been widely attributed to carnosic acid (CA). Passive extractions of CA have been performed in water by using five commercially available short-chain alkyl polyglycosides (APG) with alkyl chain lengths ranging from 4 to 10 carbon atoms and polar heads composed of pentoses and/or glucoses. APGs are nontoxic amphiphiles with high biodegradability. Their solubilizing capacity for CA has been determined, highlighting heptyl glucoside (C7Glu) as the most efficient one, followed by 2-ethylhexyl glucoside (C6,–2Glu) and isoamyl xyloside (iC5Xyl). However, iC5Xyl exhibited the highest selectivity toward CA solubilization as compared to ursolic acid (UA), a potential coextracted compound of rosemary leaves. In addition, it was found to be the most efficient amphiphile to extract CA from both ground and whole rosemary leaves. To optimize the maceration process and the recovery of the extract, a full factorial design 24 was performed investigating iC5Xyl concentration, temperature, stirring, and extraction time. A high concentration of hydrotrope was found to be the most important condition to optimize the maceration step, while the temperature particularly increases the yield, but in detriment of the CA content in the final dried extract.Show less >
Show more >Rosemary (Rosmarinus officinalis L.) is a Mediterranean herb known for its high antioxidant power that has been widely attributed to carnosic acid (CA). Passive extractions of CA have been performed in water by using five commercially available short-chain alkyl polyglycosides (APG) with alkyl chain lengths ranging from 4 to 10 carbon atoms and polar heads composed of pentoses and/or glucoses. APGs are nontoxic amphiphiles with high biodegradability. Their solubilizing capacity for CA has been determined, highlighting heptyl glucoside (C7Glu) as the most efficient one, followed by 2-ethylhexyl glucoside (C6,–2Glu) and isoamyl xyloside (iC5Xyl). However, iC5Xyl exhibited the highest selectivity toward CA solubilization as compared to ursolic acid (UA), a potential coextracted compound of rosemary leaves. In addition, it was found to be the most efficient amphiphile to extract CA from both ground and whole rosemary leaves. To optimize the maceration process and the recovery of the extract, a full factorial design 24 was performed investigating iC5Xyl concentration, temperature, stirring, and extraction time. A high concentration of hydrotrope was found to be the most important condition to optimize the maceration step, while the temperature particularly increases the yield, but in detriment of the CA content in the final dried extract.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Non spécifiée
Popular science :
Non
Administrative institution(s) :
CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Collections :
Research team(s) :
Colloïdes catalyse oxydation (CÏSCO)
Submission date :
2022-03-24T09:02:25Z
2024-01-15T15:58:26Z
2024-01-15T15:58:26Z