Titre :

Flammability properties of intumescent vinyl acetate–ethylene copolymer emulsion including natural carbonization agent

Auteur(s) :

Lu, Jinhan [Auteur]
Chinese Academy of Forestry
Li, Luming [Auteur]
Jiang, Peng [Auteur]
Chen, Zhilin [Auteur]
Fontaine, Gaelle [Auteur]
174496|||Unité Matériaux et Transformations - UMR 8207 [UMET]
120930|||Centrale Lille
Zhang, Yahui [Auteur]
Yu, Guoping [Auteur]
Bourbigot, Serge [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207

Titre de la revue :

Polymer

Nom court de la revue :

Polymer

Numéro :

245

Pagination :

124709

Éditeur :

Elsevier BV

Date de publication :

2022-04

ISSN :

0032-3861

Mot(s)-clé(s) en anglais :

Sodium lignosulfonate
Intumescent flame retardant
Thermal degradation
Bubble-shaped

Discipline(s) HAL :

Chimie/Matériaux
Chimie/Polymères

Résumé en anglais : [en]

Melamine amino trimethyl phosphate (M-AT) has been mixed with bio-based starch, chitosan, or sodium lignosulfonate (SL), and used to prepare an intumescent flame retardant (IFR) vinyl acetate-ethylene copolymer emulsion ...
Lire la suite >Melamine amino trimethyl phosphate (M-AT) has been mixed with bio-based starch, chitosan, or sodium lignosulfonate (SL), and used to prepare an intumescent flame retardant (IFR) vinyl acetate-ethylene copolymer emulsion (VAE), which might be used for the formulation of adhesives, coatings, etc. The goal was to meet the performance requirements especially with respect to flame retardance and mechanical properties. The flammability of VAE adhesives was assessed using limiting oxygen index (LOI), UL-94 vertical burning, and cone calorimetry tests (CCT). The presence of 30 wt% of the M-AT/SL compounds (mass ratio of M-AT to SL was 3:1) in VAE polymer brought a 73% reduction in peak of heat release rate (139.2-37.1 kW/m(2)) in CCT. The LOI was increased to 31.5 from 20, the UL94 grade was upgraded to V-0 (sample thickness: 5 mm). The formation of bubble-shaped char layer can be promoted by polyphosphoric acid and benzenesulfonic acid along with ammonia and sulfur dioxide, which generated by the thermal decomposition of synthesized M-AT and SL during combustion of the polymer. In addition, the incorporation of 30 wt% M-AT/SL compounds in VAE matrix leaded to a 56% and 40% increasement in tensile strength and elongation at break tests, respectively compared to the pure one. This work offers a green and novel method for the production of high-performance VAE adhesives with fire resistance propertiesLire moins >

Langue :

Anglais

Comité de lecture :

Oui

Audience :

Internationale

Vulgarisation :

Non

Établissement(s) :

Université de Lille
CNRS
INRAE
ENSCL

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Équipe(s) de recherche :

Ingénierie des Systèmes Polymères

Date de dépôt :

2022-05-18T15:56:07Z
2022-05-23T08:59:41Z