Title :

Enhancing Cycling Stability and Specific Capacitance of Vanadium Nitride Electrodes by Tuning Electrolyte Composition

Author(s) :

Haye, Emile [Auteur]
Miao, Yuanyuan [Auteur]
NanoBioInterfaces - IEMN [NBI - IEMN]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Pilloud, David [Auteur]
Institut Jean Lamour [IJL]
Douard, Camille [Auteur]
Institut des Matériaux Jean Rouxel [IMN]
Boukherroub, Rabah [Auteur]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Pierson, Jean-François [Auteur]
Institut Jean Lamour [IJL]
Brousse, Thierry [Auteur]
Institut des Matériaux Jean Rouxel [IMN]
Lucas, Stéphane [Auteur]
Université de Namur [Namur] [UNamur]
Houssiau, Laurent [Auteur]
Pireaux, Jean-Jacques [Auteur]
Achour, Amine [Auteur]

Journal title :

Journal of The Electrochemical Society

Pages :

063503, 8 pages

Publisher :

Electrochemical Society

Publication date :

2022-06-06

ISSN :

0013-4651

English keyword(s) :

Vanadium nitride
Thin film electrode
Cycling stability
Pseudocapacitance

HAL domain(s) :

Sciences de l'ingénieur [physics]

English abstract : [en]

In this study, the tuning of the KOH electrolyte composition is proposed as a strategy to drastically limit the capacitance fade of vanadium nitride (VN) electrode. We demonstrate that the use of a V5+ (as VO43- vanadates ...
Show more >In this study, the tuning of the KOH electrolyte composition is proposed as a strategy to drastically limit the capacitance fade of vanadium nitride (VN) electrode. We demonstrate that the use of a V5+ (as VO43- vanadates anions) containing KOH electrolyte enhances the cycling stability of VN thin film electrode : a loss of 59% of the capacitance is observed for the electrode tested in KOH over 3000 consecutive cycles. After V5+ addition in the electrolyte, the capacitance fade is decreased to 23%. Furthermore, the presence of V5+ species in the solution leads to VN capacitance enhancement from 379 mF cm-2 for V5+ ions free electrolyte up to 577 mF cm-2 at 5 mV s-1 for V5+-containing KOH solution. The enhanced cycling stability is attributed to the stabilization of an oxide/oxynitride layer at the VN surface, instead of its dissolution, thanks to the chemical equilibrium shift of the VN dissolution reaction. This simple and innovative strategy consisting in tuning the electrolyte composition opens new pathways for other systems that suffer from electrode dissolution in the electrolyte while being electrochemically cycled.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

ANR Project :

Laboratory of excellency for electrochemical energy storage

Collections :

• Institut d'Électronique, de Microélectronique et de Nanotechnologie (IEMN) - UMR 8520

Source :

Harvested from HAL