Title :

Multiscale observation of the fatigue-induced damage mechanisms in carbon-black filled styrene-butadiene rubber

Author(s) :

Dinari, Amina [Auteur]
Chaabane, Makram [Auteur]
Benameur, Tarek [Auteur]
Guo, Qiang [Auteur]
Gloaguen, Jean-Michel [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Zairi, Fahmi [Auteur]
Laboratoire Génie Civil et géo-Environnement (LGCgE) - ULR 4515

Journal title :

Macromolecular Materials and Engineering

Abbreviated title :

Macromol. Mater. Eng.

Volume number :

-

Publication date :

2020-06-30

ISSN :

1438-7492

Keyword(s) :

filled styrene-butadiene rubbers
damage mechanisms
ATR-FTIR spectroscopy
X-ray computed tomography
tension cyclic loading

HAL domain(s) :

Sciences du Vivant [q-bio]

English abstract : [en]

Filled rubber materials exhibit a complex macroresponse characterized by stress softening, hysteresis, and dissipative heating when they are cyclically loaded. The relationship of these inelastic features to the microstructure ...
Show more >Filled rubber materials exhibit a complex macroresponse characterized by stress softening, hysteresis, and dissipative heating when they are cyclically loaded. The relationship of these inelastic features to the microstructure changes is far from being fully established. This paper deals with the damage mechanisms in sulfur-vulcanized styrene-butadiene rubber (SBR) specimens in the diablo form reinforced with carbon-black (CB) and zinc-oxide (ZnO) fillers, and submitted to tension cyclic loading at room temperature. The microstructure alteration is characterized at different relevant scales and at different zones of the diabolo specimen by means of various technologies in the aim to report valuable insights about the mechanisms responsible for the macroresponse of this rubber-filler material system. IR absorption spectra reveal that increasing filler content induces more interfacial interaction between CB and SBR chains. The environmental scanning electron microscopy (ESEM) observations show relevant altered morphologies of elastomeric chains with a predominant effect of both CB and ZnO fillers. A mesoscale observation of material density variation is presented using X-ray computed tomography and the results are compared with those issued from ESEM.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

CNRS
ENSCL
IMT Lille Douai
INRA
Institut Catholique Lille
Univ. Artois
Université de Lille

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Ingénierie des Systèmes Polymères

Submission date :

2022-06-15T13:59:35Z
2023-12-19T16:23:11Z