Title :

4-phenyl-decahydro-1H-1,5-benzodiazepin-2-one as novel and effective corrosion inhibitor for carbon steel in 1 M HCl solution: A combined experimental and empirical studies

Author(s) :

Al Garadi, W. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]
Jrajri, K. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]
El Faydy, M. [Auteur]
Université Ibn Tofaïl [UIT]
Benhiba, F. [Auteur]
Université Ibn Tofaïl [UIT]
El Ghayati, L. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]
Sebbar, N.K. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]
Essassi, E.M. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]
Warad, I. [Auteur]
An-Najah National University
Guenbour, A. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]
Bellaouchou, A. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]
Jama, charafeddine [Auteur]
1002334|||Unité Matériaux et Transformations - UMR 8207 [UMET]
374570|||Université de Lille
Alsalme, A. [Auteur]
King Saud University [Riyadh] [KSU]
Zarrouk, A. [Auteur]
Université Mohammed V de Rabat [Agdal] [UM5]

Journal title :

Journal of the Indian Chemical Society

Abbreviated title :

Journal of the Indian Chemical Society

Volume number :

99

Pages :

100742

Publisher :

Elsevier BV

Publication date :

2022-11

ISSN :

0019-4522

English keyword(s) :

Benzodiazepine
Carbon steel corrosion
Electrochemical measurements
SEM/DFT
Molecular dynamics simulation

HAL domain(s) :

Chimie/Catalyse
Chimie/Polymères

English abstract : [en]

The heterocyclic system, namely 4-phenyl-decahydro-1H-1,5-benzodiazepin-2-one (POBZ) was inspected as a corrosion inhibitor of carbon steel (CS) in a 1 M HCl medium through electrochemical impedance spectroscopy (EIS), ...
Show more >The heterocyclic system, namely 4-phenyl-decahydro-1H-1,5-benzodiazepin-2-one (POBZ) was inspected as a corrosion inhibitor of carbon steel (CS) in a 1 M HCl medium through electrochemical impedance spectroscopy (EIS), potentiodynamic polarization measurements (PDP), and scanning electron microscopy (SEM). The experimental data indicate that the inhibiting action augments with augmenting POBZ amount and reduces with augmenting temperature. The inhibiting action efficiency of 90.98% is obtained with 0.001 M at 303 K. The potentiodynamic polarization (PDP) results mentioned that the POBZ is of mixed type. The adsorption of POBZ on the CS followed Langmuir isotherm. SEM exams affirmed that the steel surface is smooth in presence of POBZ. In light of the calculations of density functional theory (DFT) and molecular dynamics simulation, the mechanism of POBZ inhibitory activity was addressed.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

Université de Lille
CNRS
INRAE
ENSCL

Collections :

• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Procédés de Recyclage et de Fonctionnalisation (PReF)

Submission date :

2022-10-20T20:16:43Z
2022-10-21T07:51:12Z
2022-10-21T08:02:50Z